Vedernikov, Andrei
Professor
所属大学: University of Maryland
所属学院: Department of Chemistry & Biochemistry
邮箱:
avederni@umd.edu
个人主页:
http://www2.chem.umd.edu/groups/vedernikov/VGroup_start_page.htm
个人简介
Doctor of Science degree, Department of Chemistry, Division of Organic Chemistry, Kazan State University (KSU), Russia, 2000 Ph.D. degree, Department of Chemistry, KSU, 1986 Graduate student, KSU, 1983-1986 M.S. degree, Summa cum Laude, KSU, 1983
研究领域
“Green” synthetic strategies: the use of O2 and H2O2 for selective C‑H and CC functionalization. Organotransition metal chemistry, experimental and computational (DFT). Organometallic reaction mechanisms.
Homogeneous catalysis with transition metal complexes
近期论文
Liu, W.-G.; Sberegaeva, A.V.; Nielsen, R.J.; Goddard, W.A. III, Vedernikov, A.N. "The Mechanism of O2 Activation and Methanol Production by (di(2-pyridyl)methanesulfonate)PtIIMe(OHn)(2-n)- Complex from Theory with Validation from Experiment", J. Am. Chem. Soc. 2014, 136, 2335-2341. Sberegaeva, A.V.; Liu, W.-G.; Nielsen, R.J.; Goddard, W.A. III, Vedernikov, A.V. "Mechanistic Study of the Oxidation of a Methyl Platinum(II) Complex with O2 in Water: PtIIMe–to–PtIVMe and PtIIMe–to–PtIVMe2 Reactivity", J. Am. Chem. Soc. 2014, 136, 4761-4768. Pal, S.; Zavalij, P.Y.; Vedernikov, A.N. "Oxidative C(sp3)-H Bond Cleavage, C-C and C=C Coupling at a Boron Center with O2 as Oxidant Mediated by Platinum(II)", Chem. Comm. 2014, 50, 5376-5378. Vedernikov, A.N. "Mechanism of the Kumada – Corriu Cross-Coupling Catalyzed by Low-Coordinate Bis-Amido Nickel Complexes: Identification of NiI, NiII and NiIII Catalytic Intermediates", ChemCatChem 2014, 6, 2490-2492. Oloo, W.N.; Zavalij, P.Y.; Vedernikov, A.N. "PdIV Monohydrocarbyls: Mechanistic Study of the Ligand-Enabled Oxidation of PdII Complexes with H2O2 in Water", Organometallics, 2013, 32, 5601-5614. Wang, D.; Zavalij, P.Y.; Vedernikov, A.N. "Aerobic C-H Acetoxylation of 8-Methylquinoline in PdII – Pyridinecarboxylic Acids Systems: Some Structure – Reactivity Relationships", Organometallics, 2013, 32, 4882- 4891. Dubinsky-Davidchik, I.S.; Goldberg, I.; Vigalok, A.; Vedernikov, A.N. "Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl -naphthyl Pt(IV) difluorides to produce -arylnaphthyl Pt(II) complexes", Chem. Comm. 2013, 49, 3446-3448. Vedernikov, A.N. "PdII/PdIV redox couple mediated C-X Bond Formation" In C-H and C-X Bond Functionalization. Transition Metal Mediation. RSC Publishing: 2013, 108-121. Dubinsky-Davidchik, I.S.; Potash, S.; Goldberg, I.; Vigalok, A.; Vedernikov, A.N. "Electrophilic Fluorination of Organoplatinum(II) Iodides: Iodine and Platinum Atoms As Competing Fluorination Sites", J. Am. Chem. Soc. 2012, 134, 14027-14032. Pal, S.; Vedernikov, A.N. "Oxidation of Dimethyldi(2-pyridyl)borato PtIIMen Complexes, n = 1, 0, with H2O2: Tandem B-to-Pt Methyl Group Migration and Formation of C-O Bond", Dalton Trans. 2012, 41, 8116-8122. Kocak, F.; Downing, D.; Zavalij, P.; Lam, Y.-F.; Vedernikov, A.; Eichhorn, B. "The Surprising Acid-Base and Ion- Sequestration Chemistry of Sn94-: HSn93-, Ni@HSn93- and the Sn93- Ion Revisited", J. Am. Chem. Soc. 2012, 134, 9733-9740. Vedernikov, A.N., "Direct Functionalization of M-C (M = PtII, PdII) Bonds Using Environmentally Benign Oxidants, O2 and H2O2", Acc. Chem. Res. 2012, 45, 803-813. Khusnutdinova, J.R.; Newman, L.; Vedernikov, A.N. "Selective and Efficient Oxidation of Ethylene to Ethylene Glycol Acetates with H2O2 Catalyzed by Pd(OAc)2 – Di(2-pyridiyl)ketone – Di(2-pyridyl)methanesulfonate System", J. Organomet. Chem. 2011, 696, 3998-4006. Khusnutdinova, J.R.; Zavalij, P.Y.; Vedernikov, A.N. "Allylic C-H Deprotonation of Olefins with PtII(OH) to Form 3- Allyl PtII Complexes in Water and Aprotic Organic Solvents", Organometallics 2011, 30, 3392-3399. Khusnutdinova, J.R.; Maiorana, A.S.; Zavalij, Vedernikov, A.N. "Stoichiometric Aerobic Aminohydroxylation of Ethylene Mediated by dpms – Platinum Complexes (dmps = di(2-pyridyl)methanesulfonate)", Inorg. Chim. Acta
2011, 369, 274-286.