Electrophilic Fluorination Using Hypervalent Iodine Reagents Fluorinated Reformatsky Reaction Fluorous Catalysis

“Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride" G. C. Geary, E. G. Hope, K. Singh and A. M. Stuart, Chem. Commun., 2013, DOI: 10.1039/C3CC44792H. “Enantioselective Reformatsky reaction of ethyl iododifluoroacetate with aromatic ketones.” M. Fornalczyk, K. Singh and A. M. Stuart, Org. Biomol. Chem., 2012, 10, 3332-3342. “Syntheses of a-fluoro-b-hydroxy esters by an enantioselective Reformatsky-type reaction." M. Fornalczyk, K. Singh and A. M. Stuart, Chem. Commun., 2012, 48, 3500-3502. (Highlighted in Synfacts, 2012, 8, 656) “Separation, recovery and recycling of a fluorous-tagged nickel catalyst using fluorous solid-phase extraction.” B. Croxtall, E. G. Hope and A. M. Stuart, Chem. Commun., 2003, 2430-2431. “A recyclable perfluoroalkylated PCP pincer palladium complex.” D. Duncan, E. G. Hope, K. Singh and A. M. Stuart, Dalton Trans., 2011, 40, 1998-2005. “Novel insoluble perfluoroalkylated polymers: new solid supports for supported fluorous catalysis.” N. Audic, P. W. Dyer, E. G. Hope, A. M. Stuart and S. Suhard, Adv. Synth. Catal., 2010, 352, 2241-50. (Highlighted in Synfacts, 2010, 12, 1432) “Di(1H,1H,2H,2H-perfluorooctyl)-dibenzo-18-crown-6: A “light fluorous” recyclable phase transfer catalyst.” B. Gourdet, K. Singh, A. M. Stuart and J. A. Vidal, J. Fluorine Chem., 2010, 131, 1133-1143. “Perfluoroalkylated 4,13-diaza-18-crown-6 ethers: Synthesis, phase-transfer catalysis, and recycling studies.” A. M. Stuart and J. A. Vidal, J. Org. Chem., 2007, 72, 3735-3740. “Syntheses and properties of fluorous quaternary phosphonium salts that bear four ponytails; new candidates for phase transfer catalysts and ionic liquids.” C. Emnet, K. M. Weber, J. A. Vidal, C. S. Consorti, A. M. Stuart and J. A. Gladysz, Adv. Synth. Catal., 2006, 348, 1625-1634.