Ligand design, asymmetric catalysis, alkene polymerisation catalysis

A new synthesis of charge-neutral tris-pyrazolyl and -methimazolyl borate ligands. P. J. Bailey, L. Budd, F. A. Cavaco, S. Parsons, F. Rudolphi, A. Sanchez-Perucha, F. J. White, Chem. Eur. J. 2010, 16, 2819-2829 Ambidentate character of the 6 aminofulvene-2-aldiminate (AFA) ligand containing both diimine and cyclopentadienyl donors. P. J. Bailey, M. Melchionna, S. Parsons, Organometallics, 2007, 26, 128-135 Tripodal borate ligands from tris(dimethylamino)borane: the first synthesis of a chiral C3-symmetric tris(methimazolyl)borate ligand. P. J. Bailey, C. McCormack, A. Sanchez-Peruscha, S. Parsons, F. Rudolfi, P. Wood, Dalton Trans., 2007, 476