d- and f-block organometallic chemistry; small molecule activation chemistry; homogeneous catalysis

C-H Bond Activation by f-Block Complexes. P. L. Arnold, M. W. McMullon, J. Rieb, F. E. Kuhn, Angew. Chem. Int. Ed. 2015, 54, 82-100. New chemistry from an old reagent: Mono- and dinuclear macrocyclic uranium(III) complexes from U(BH4)3(THF)2. P. L. Arnold, C. J. Stevens, J. H. Farnaby, M. G. Gardiner, G. S. Nichol, J. B. Love JACS 2014, 136, 10218-10221. Thorium mono- and bis(imido) complexes made by reprotonation of cyclo-metalated amides. N. L. Bell, L. Maron, P. L. Arnold JACS 2015, 137, 10492–10495. Strongly coupled binuclear uranium-oxo complexes from uranyl oxo rearrangement and reductive silylation. P. L. Arnold, G. M. Jones, S. O. Odoh, G. Schreckenbach, N. Magnani, J. B. Love. Nature Chem. 2012, 4, 221-227. Spontaneous reduction and C-H borylation of arenes mediated by uranium(III) disproportionation.P. L. Arnold, S. M. Mansell, L. Maron, D. McKay. Nature Chem. 2012, 4, 668-674. Reduction and selective oxo group silylation of the uranyl dication. P. L. Arnold, D. Patel, C. Wilson, J. B. Love. Nature 2008, 451, 315-317. Small molecule activation by uranium tris(aryloxides): Experimental and computational studies of binding of N2, coupling of CO, and deoxygenation insertion of CO2 under ambient conditions. S. M. Mansell, N. Kaltsoyannis, P. L. Arnold. JACS 2011, 133, 9036-9051.