ChevronTexaco Graduate Fellowship 2005 NIH Ruth L. Kirschstein NRSA Postdoctoral Fellow 2007-2010 NSF Career Award 2014 Alfred P. Sloan Foundation Research Fellow 2014

Environmental/Inorganic/Organic

Environmental Inorganic Organic

McCarthy, S.M.; Lin, Y.-C.; Devarajan, D.; Chang, J.-W.; Yennawar, H.; Rioux, R.M.; Ess, D.H.; Radosevich, A.T. "Intermolecular N-H Oxidative Addition of Ammonia, Alkylamines, and Arylamines to a Planar σ3-Phosphorus Compound via an Entropy-Controlled Electrophilic Mechanism." J. Am. Chem. Soc. 2014, doi: 10.1021/ja412469e. Reichl, K.D; Ess, D.H.; Radosevich, A.T. "Catalyzing Pyramidal Inversion: Configurational Lability of P-Stereogenic Phosphines via Single Electron Oxidation." J. Am. Chem. Soc. 2013, 135, 9354. Zhao, W.; Fink, D.M.; Labutta, C.A.; Radosevich, A.T. "A Csp3–Csp3 Bond Forming Reductive Condensation of α-Keto Esters and Enolizable Carbon Pronucleophiles." Org. Lett. 2013, 15, 3090. Sathe, A.A.; Hartline, D.R.; Radosevich, A.T. "A Synthesis of α-Amino Acids via Direct Reductive Carboxylation of Imines with Carbon Dioxide." Chem. Comm. 2013, 49, 5040. Wang, S.R.; Radosevich, A.T. "Reductive Homocondensation of Benzylidene- and Alkylidenepyruvate Esters by a P(NMe2)3-Mediated Tandem Reaction." Org. Lett. 2013, 15, 1926. Miller, E.J.; Zhao, W.; Herr, J.D.; Radosevich, A.T. "A Nonmetal Approach to α- Heterofunctionalized Carbonyl Derivatives by Formal Reductive X-H Insertion." Angew. Chem. Int. Ed. 2012, 51, 10605. Dunn, N.L.; Radosevich, A.T. "Main Group Redox Catalysis: Reversible P(III)/P(V) Redox Cycling at a Phosphorus Platform." J. Am. Chem. Soc. 2012, 134, 11330.