Synthetic Organic Physical Chemistry Solid State Physical Chemistry

Design and synthesis of molecular conductors and other functional materials based on low molecular weight organics. Exploitation of itinerant electron system having multi-instability.

Y. Yoshida, M. Maesato, M. Ishikawa, Y. Nakano, T. Hiramatsu, H. Yamochi, G. Saito, "Charge-Transfer Solids Using Nucleobases: Supramolecular Architectures Composed of Cytosine and [Ni(dmit)2] Assembled by Multiple Hydrogen Bonds and Heteroatomic Contacts", Chem. Eur. J., 19(37), 12325-12335 (2013) M. Gao, C. Lu, H. Jean-Ruel, L.C. Liu, A. Marx, K. Onda, S. Koshihara, Y. Nakano, X.F. Shao, T. Hiramatsu, G. Saito, H. Yamochi, R.R. Cooney, G. Moriena, G. Sciaini, R.J.D. Miller, "Mapping Molecular Motions Leading to Charge Delocalization with Ultrabright Electrons", Nature, 496(7445), 343-346 (2013) D.V. Konarev, M. Ishikawa, S.S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya, "Synthesis, Structural and Magnetic Properties of Ternary Complexes of (Me4P+)•{[Fe(I)Pc(-2)]-}•Triptycene and (Me4P+)•{[Fe(I)Pc(-2)]-}•(N,N,N',N'-Tetrabenzyl-p-phenylenediamine)0.5 with Iron(I) Phthalocyanine Anions", Inorg. Chem., 52(7), 3851-3859 (2013) G. Saito, H. Hosoda, Y. Yoshida, J. Hagiwara, K. Nishimura, H. Yamochi, A. Otsuka, T. Hiramatsu, Y. Shimazaki, K. Kirakci, S. Cordier, C. Perrin, "Synthesis and Properties of Charge-transfer Solids with Cluster Units [Mo6X14]2- (X = Br, I)", J. Mater. Chem., 22(37), 19774-19791 (2012) T. Shirahata, K. Shiratori, S. Kumeta, T. Kawamoto, T. Ishikawa, S. Koshihara, Y. Nakano, H. Yamochi, Y. Misaki, T. Mori, "Structural Transitions from Triangular to Square Molecular Arrangements in the Quasi-One-Dimensional Molecular Conductors (DMEDO-TTF)2XF6 (X = P, As, and Sb)", J. Am. Chem. Soc., 134(32), 13330-13340 (2012) T. Haneda, A. Tracz, G. Saito, H. Yamochi, "Continuous and Discontinuous Water Release/Intake of (BEDO-TTF)2Br(H2O)3 Micro Crystals Embedded in Polymer Film", J. Mater. Chem., 21(5), 1621-1626 (2011) T. Murata, X.F. Shao, Y. Nakano, H. Yamochi, M. Uruichi, K. Yakushi, G. Saito, K. Tanaka, "Tuning of Multi-instabilities in Organic Alloy, [(EDO-TTF)1-x(MeEDO-TTF)x]2PF6", Chem. Mater., 22(10), 3121–3132 (2010) S. Fujio, K. Tanaka, H. Inui, R. Ueji, N. Sumida, H. Yamochi, G. Saito, "Enantiomorph identification and stacking faults in -(BEDT-TTF)2Cu(NCS)2 by convergent-beam electron diffraction", J. Appl. Cryst., 42(3), 433-441 (2009) X.F. Shao, Y. Yoshida, Y. Nakano, H. Yamochi, M. Sakata, M. Maesato, A. Otsuka, G. Saito, S. Koshihara, "Prediction of the Electronic Structure via Molecular Stacking Mode of Radical Cation Salts Based on Asymmetric Donor Molecule MeEDO-TTF", Chem. Mater., 21(6), 1085-1095 (2009)

H. Yamochi, S. Koshihara, Organic Metal (EDO-TTF)2PF6 with Multi-instability", Sci. Technol. Adv. Mater., 10(2), 024305/1-6 (2009)