Lin, H-.J.; Siretanu, D.; Dickie, D.A.; Subedi, D.; Scepaniak, J.J.; Mitcov, D.; Clérac, R.; Smith, J.M. "Steric and Electronic Control of the Spin State in Three-Fold Symmetric, Four-Coordinate Iron(II) Complexes" J. Am. Chem. Soc. 2014, 136, 13326-13332. Juarez, R.A.; Lee, W.-T.; Smith, J.M.; Wang, H. "Computational Evaluation of Tris(carbene)borate Donor Properties in {NiNO}10 Complexes" Dalton Trans., 2014, 43, 14689-14695. Cutsail, G.E. III; Stein, B.W.; Subedi, D.; Smith, J.M.; Kirk, M.L.; Hoffman, B.M. "EPR, ENDOR and Electronic Structure Studies of the Jahn-Teller Distortion in an FeV Nitride" J. Am. Chem. Soc., 2014, 136, 12323-12336. Lee, W.-T.; Muñoz, S.B. III; Dickie, D.A.; Smith, J.M. "Ligand Modification Transforms a Catalase Mimic into a Water Oxidation Catalyst" Angew. Chem., Int. Ed., 2014, 53, 9856-9859. Lee, W.-T.; Jeon, I.-R.; Xu, S.; Dickie, D.A.; Smith, J.M. "Low-Coordinate Iron(II) Complexes of a Bulky Bis(carbene)borate Ligand" Organometallics, 2014, 33, 5654-5659 (invited contribution to a special issue on earth abundant metals). Lee, W.-T.; Juarez, R.A.; Scepaniak, J.J.; Muñoz, S.B; Dickie, D.A.; Wang, H.; Smith, J.M. "Reaction of an Iron(IV) Nitrido Complex with Cyclohexadienes: Cycloaddition and Hydrogen Atom Abstraction" Inorg. Chem., 2014, 53, 8425-8430. Smith, J.M. "Reactive Transition Metal Nitride Complexes" Progress Inorg. Chem. 2014, 58, 417-470 (invited review). Mathonière, C.; Lin, H.-J.; Siretu, D.; Clérac, R.; Smith, J.M. "Photoinduced Single-Molecule Magnet Properties in a Four-Coordinate Iron(II) Spin Crossover Complex" J. Am. Chem. Soc. 2013, 135, 19083-19086. Aither 2013:Users:Rodolphe:Desktop:JACS, Jeremy SCMM:TOC3.psd Lee, W.-T.; Dickie, D.A.; Metta-Magaña, A.; Smith, J.M. "A Tripodal Ligand Constructed from Mesoionic Carbene Donors" Inorg. Chem. 2013, 52, 12842-12846. Scepaniak, J.J.; Margarit, C.G.; Bontchev, R.P.; Smith, J.M. "Cobalt Azide Complexes with a Tris(carbene)borate Ligand Scaffold" Acta Cryst. 2013, C69, 968-971 (invited contribution for a special issue on scorpionate ligands). Lee, W.-T.; Xu, S.; Dickie, D.A.; Smith, J.M. "A Robust Mn Catalyst for H2O2 Disproportionation in Aqueous Solution" Eur. J. Inorg. Chem. 2013, 3867-3873(invited contribution for a cluster issue on small molecule activation). Forshaw, A.P.; Smith, J.M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, S.A.; Harris, T.D.; Kuranadasa, H.I.; Zadrozny, J.M.; Schnegg, A.; Holldack, K.; Jackson, T.A; Alamiri, A.; Barnes, D.M.; Telser, J. "Low-Spin Hexa-Coordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes" Inorg. Chem. 2013, 52, 144-159. http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/inocaj/2013/inocaj.2013.52.issue-1/ic301630d/production/images/large/ic-2012-01630d_0009.jpeg Muñoz, S.B. III; Foster, W.K.; Lin, H.-J.; Margarit, C.G.; Dickie, D.A.; Smith, J.M. "Tris(carbene)borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene and 1,3,4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO}10 complexes." Inorg. Chem. 2012, 51, 12660-12668. Smith, J.M.; Mayberry, D.E.; Margarit, C.G.; Sutter, J.; Wang, H.; Meyer, K.; Bontchev, R.P. "N–O Bond Homolysis of an Iron(II) TEMPO Complex to Yield an Iron(III) Oxo" J. Am. Chem. Soc. 2012, 134, 6516-6519. Smith, J.M.; Subedi, D. "The Structure and Reactivity of Iron Nitride Complexes" Dalton Trans. 2012, 41, 1423-1429 (invited contribution). Scepaniak, J.J.; Margarit, C.G.; Harvey, J.N.; Smith, J.M. "Nitrogen Atom Transfer from Iron(IV) Nitrido Complexes. A Dual-Nature Transition State for Nitrogen Atom Transfer" Inorg. Chem. 2011, 50, 9508-9517. Scepaniak, J.J.; Bontchev, R.P.; Johnson, D.L.; Smith, J.M. "Snapshots of Complete Nitrogen Atom Transfer from an Iron(IV) Nitrido Complex." Angew. Chem. Int. Ed. 2011, 50,6630-6633. Scepaniak, J.J.; Harris, T.D.; Vogel, C.S.; Sutter, J.; Meyer, K.; Smith, J.M. "Spin Crossover in a Four-Coordinate Iron(II) Complex" J. Am. Chem. Soc. 2011, 133, 3824-3827. Scepaniak, J.J.; Vogel, C.S.; Khusniyarov, M.M.; Heinemann, F.W.; Meyer, K.; Smith, J.M. "Synthesis, Structure, and Reactivity of an Iron(V) Nitride" Science 2011, 331, 1049-1052. Smith, J.M.; Long, J.R. "First-Row Transition Metal Complexes of the Strongly Donating Pentadentate Ligand PY4Im" Inorg. Chem. 2010, 49, 11223-11230. http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/inocaj/2010/inocaj.2010.49.issue-23/ic1018407/production/images/large/ic-2010-018407_0013.jpeg Nieto, I.; Bontchev, R.P.; Ozarowski, A.; Smirnov, D.; Krzystek, J.; Telser, J.; Smith, J.M. "Synthesis and Spectroscopic Investigations of Four-Coordinate Nickel Complexes Supported by a Strongly Donating Scorpionate Ligand" Inorg. Chim. Acta 2009, 362, 4449-4460 (invited contribution in honor of Jerry Trofimenko). Scepaniak, J.J.; Young, J.A; Bontchev, R.P.; Smith, J.M. "Formation of Ammonia from an Iron Nitrido Complex" Angew. Chem. Int. Ed. 2009, 48, 3158-3160. Ding, F.; Smith, J.M.; Wang, H. "First-Principles DFT Calculation of pKa’s for Organic Acids in Non-Aqueous Solution" J. Org. Chem. 2009, 74, 2679-2691. Smith, J.M. "Strongly Donating Scorpionates" Comments Inorg. Chem. 2008, 29, 189-233. Scepaniak, J.J.; Fulton, M.D.; Bontchev, R.P.; Duesler, E.N.; Kirk, M.L.; Smith, J.M. "Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex" J. Am. Chem. Soc. 2008, 130, 10515-10517. Synopsis Figure Nieto, I.; Bontchev, R.P.; Smith, J.M. "Synthesis of a bulky bis(carbene)borate ligand. Contrasting structures of homoleptic nickel(II) bis(pyrazoyl)borate and bis(carbene)borate complexes." Eur. J. Inorg. Chem., 2008, 2476-2480. Nieto, I.; Ding, F.; Bontchev, R.P.; Wang, H.; Smith, J.M. "Thermodynamics of Hydrogen Atom Transfer to a High Valent Iron Imido Complex" J. Am. Chem. Soc. 2008, 130, 2716-2717. Forshaw, A.P.; Bontchev, R.P.; Smith, J.M. "Oxidation of the Tris(carbene)borate Complex PhB(MeIm)3MnI(CO)3 to MnIV[PhB(MeIm)3]2(OTf)2" Inorg. Chem., 2007, 46, 3792-3794. Cowley, R.E.; Bontchev, R.P.; Sorrell, J.; Sarracino, O.; Feng, Y.; Wang; H.; Smith; J.M. "Formation of a Cobalt(III) Imido from a Cobalt(II) Amido Complex. Evidence for Proton-Coupled Electron Transfer" J. Am. Chem. Soc., 2007, 129, 2424-2425. Cowley, R.E.; Bontchev, R.P.; Duesler, E.N.; Smith, J.M. "Removing the Sting from the Tail. Reversible Protonation of Scorpionate Ligands in Cobalt(II) Tris(carbene)borate Complexes" Inorg. Chem., 2006, 45, 9771-9779. Nieto, I.; Cervantes-Lee, F. Smith, J.M. "A New Synthetic Route to Bulky ‘Second Generation’ Tris(imidazol-2-ylidene)borates: Synthesis of a Four-Coordinate Iron(II) Complex", Chem. Commun., 2005, 3811-3813.