Inorganic Chemistry

A cis-Divacant Octahedral and Mononuclear Iron(IV) Imide, Searles, Keith; Fortier, Skye; Khusniyarov, Marat M.; Carroll, Patrick J.; Sutter, Joerg; Meyer, Karsten; Mindiola, Daniel J.; Caulton, Kenneth G., Angew. Chem. Int. Ed., 2014, 126(51), 14363-14367. DOI: 10.1002/ange.201407156. Coordination Characteristics of a Pincer Ligand for Noninnocent Ligand Application, Cook, Brian J.; Chen, Chun-Hsing; Pink, Maren; Lord, Richard L.; Caulton, Kenneth G., Inorg. Chem., 2014, Submitted (5-2-2014). In Search of Redox Non-innocence between a Tetrazine Pincer Ligand and Monovalent Copper, Hui, Alice K.; Lord, Richard L.; Caulton, Kenneth G., Dalton Trans., 2014, 43(21), 7958-7963. DOI: 10.1039/C3DT52490F. Chemical Implications of Incompatible Ligand versus Metal Coordination Geometry Preferences, Hui, Alice K.; Losovyj, Yaroslav; Lord, Richard L., Caulton, Kenneth G., Inorg. Chem., 2014, 53(6), 3039-3047. DOI 10.1021/ic402866e. Mechanistic Understanding of a Silver Pyridylpyrrolide as a Catalyst for 3+2 Cyclization of a Nitrile with Diazo Ester, Flores, Jaime A.; Pal, Kuntal; Carroll, Maria E.; Pink, Maren; Karty, Jonathan A.; *Mindiola, Daniel J.; Caulton, Kenneth G., Organometallics, 2014, 33(7), 1544-1552. DOI: 10.1021/om400756t. A Tale of Hydrogen Abstraction, Initially Detected via X-ray Diffraction, Hui, Alice K.; Chen, Chun-Hsing; Terwilliger, Adam M.; Lord, Richard L., Caulton, Kenneth G., Acta Crystallogr. C Struct. Chem., 2014, 70(Pt 3), 250-255. DOI: 10.1107/S2053229614003234. Transition Metal Chlorides are Lewis Acids toward Terminal Chloride Attached to Late Transition Metals, Hui, Alice K.; Cook, Brian J.; Mindiola, Daniel J.; Caulton, Kenneth G., Inorg. Chem., 2014, 53(7), 3307-3310. DOI: 10.1021/ic402107z. Multiplying the Electron Storage Capacity of a bis-Tetrazine Pincer Ligand, Benson, Christopher R.; Hui, Alice K.; Parimal, Kumar; Cook, Brian J.; Chen, Chun-Hsing; Lord, Richard L.; Flood, Amar H.; Caulton, Kenneth G., Dalton Trans., 2014, 43(17), 6513-6524. DOI: 10.1039/C4DT00341A. Probing the Steric and Electronic Characteristics of a New Bis-Pyrrolide Pincer Ligand, Komine, Nobuyuki; Buell, Rene W.; Chen, Chun-Hsing; Hui, Alice K.; Pink, Maren; Caulton, Kenneth G., Inorg. Chem., 2014, 53(3), 1361-1369. DOI: 10.1021/ic402120r. A Dinuclear Cobalt Complex Featuring Unprecedented Anodic and Cathodic Redox Switches for Single-Molecule Magnet Activity, Fortier, Skye; Le Roy, Jennifer; Chen, Chun-Hsing; Vieru, Veacheslav; Murugesu, Muralee; Chibotaru, Liviu; Mindiola, Daniel J.; Caulton, Kenneth G., J. Am. Chem. Soc., 2013, 135(39), 14670-14678. DOI: 10.1021/ja405284t. Synthesis and Oxidative Reactivity of 2,2’-Pyridylpyrrolide Complexes of Ni(II), Tsvetkov, Nikolay; Chen, Chun-Hsing; Andino, Jose; Lord, Richard L.; Pink, Maren; Buell, René W.; Caulton, Kenneth G., Inorg. Chem., 2013, 52(16), 9511-9521. DOI: 10.1021/ic4011746. Büchner Reactions Catalyzed by a Silver(I) Pyridylpyrrolide: Understanding Arene Insertion Selectivity, Komine, Nobuyuki; Flores, Jaime A.; Pal, Kuntal; Caulton, Kenneth G.; Mindiola, Daniel J., Organometallics, 2013, 32(11), 3185-3192. DOI: 10.1021/om301240d. 2,2’-Pyridylpyrrolide Ligand Redistribution Following Reduction, Searles, Keith; Das, Atanu K.; Buell, René W.; Pink, Maren; Chen, Chun-Hsing; Pal, Kuntal; Morgan, David Gene; Mindiola, Daniel J.; Caulton, Kenneth G., Inorg. Chem., 2013, 52(9), 5611-5619. DOI: 10.1021/ic400803e. New Approaches to Functionalizing Metal-coordinated N2. Andino, Jose; Mazumder, Shivnath; Pal, Kuntal; Caulton, Kenneth G., Angew. Chem. Int. Ed., 2013, 52, 4726-4732. Reactivity of the Terminal Oxo Species ((tBu2PCH2SiMe2)2N)RhO. Tsvetkov, Nikolay; Andino, Jose; Fan, Hongjun; Verat, Alexander; Caulton, Kenneth G., Dalton Trans., 2012, 42, 6745-6755. Probing the redox non-innocence of dinuclear, three-coordinate Co(II) nindigo complexes: not simply β-diketiminate variants. Fortier, Skye; Gonzalez-del Moral, Octavio; Chen, Chun-Hsing; Pink, Maren; Le Roy, Jennifer J.; Murugesu, Muralee; Mindiola, Daniel J.; Caulton, Kenneth G., Chem. Comm. 2012, 48(90), 11082-11084. Silver(I)-Catalyzed Insertion of Carbene into Alkane C-H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanist Probe. Flores, Jaime A.; Komine, Nobuyuki; Pal, Kuntal; Pinter, Balazs; Pink, Maren; Chen, Chun-Hsing; Caulton, Kenneth G.; Mindiola, Daniel J., ACS Catal., 2012, 2(10), 2066-2078. DOI: 10.1021/cs300256b. An iridium-pyridylpyrrolide complex exhibiting reversible binding of H(2). Searles, Keith; Pink, Maren; Caulton, Kenneth G.; Mindiola, Daniel J., Dalton Trans., 2012, 41(32), 9619-9622.

Systematics and Future Projections Concerning Redox-noninnocent Amide/Imine Ligands. Caulton, Kenneth G., Eur. J. Inorg. Chem., 2012, 2012(3), 435-443. (doi: 10.1002/ejic.201100623 online 11/14/2011).