Daasbjerg, Kim 照片

Daasbjerg, Kim

Professor

所属大学: Aarhus University Denmark

所属学院: Department of Chemistry

邮箱:
kdaa@chem.au.dk

个人主页:
https://pure.au.dk/portal/en/persons/kdaa%40chem.au.dk

个人简介

Employment 2015 – present PROFESSOR, Department of Chemistry and iNANO, Aarhus University. 2010–2015 PROFESSOR MSO, Department of Chemistry and iNANO, Aarhus University. 2009–2010 ASSOCIATE PROFESSOR MSO, Department of Chemistry, Aarhus University. 2006–2009 ASSOCIATE PROFESSOR OF CHEMISTRY, Department of Chemistry, Aarhus University. 2006 VISTING PROFESSOR, Department of Chemistry, University of Padova, Italy. 1997–2006 ASSOCIATE PROFESSOR OF CHEMISTRY, Department of Chemistry, Aarhus University. 1993–1997 ASSISTANT PROFESSOR, Department of Chemistry, Aarhus University. 1993 POSTDOCTORAL FELLOW, Royal Institute of Technology, Stockholm, Sweden. Education 2006 DOCTOR OF SCIENCE DEGREE, Aarhus University 1993 PHD, Department of Chemistry, Aarhus University (Supervisor: dr. H. Lund) 1990 MASTER OF SCIENCE, Department of Chemistry, Aarhus University (Supervisor: dr. H. Lund)

研究领域

Daasbjerg’s expertise includes the development of surface modification tools as applied to the study of polymer brushes, responsive polymers, coatings, smart hybrid materials and composites involving in one or the other way carbon-based substrates. Recently, the scientific research has had its focus on fundamental aspects of graphene and its functionalization to exploit the extraordinary properties of this carbon allotrope in materials science. Finally, the combined expertise in electrochemistry, modification of surfaces, polymer brushes, and carbon materials is employed to meet a scientifically difficult challenge of great societal importance in terms of converting the greenhouse gas, carbon dioxide, to useful building blocks for the chemical industry or the energy sector.

近期论文

Electrochemical valorization of captured CO2: recent advances and future perspectives Hu, X.-M., Liang, H.-Q., Rosas-Hernández, A. & Daasbjerg, K., 2025, In: Chemical Society Reviews. 35 p. Bio-integrated carbon capture and utilization: at the interface between capture chemistry and archaeal CO2 reduction Sieborg, M. U., Nielsen, A. K. H., Ottosen, L. D. M., Daasbjerg, K. & Kofoed, M. V. W., 29 Aug 2024, In: Nature Communications. 15, 1, 7492. Effect of Variable Amine Pendants in the Secondary Coordination Sphere of Manganese Bipyridine Complexes on the Electrochemical CO2 Reduction Hong, W., Jakobsen, J. B., Golo, D., Madsen, M. R., Ahlquist, M. S. G., Skrydstrup, T., Pedersen, S. U. & Daasbjerg, K., Feb 2024, In: ChemElectroChem. 11, 4, 10 p., e202300553. Electrocatalytic dechlorination of chloroethylenes using nitrogen-doped graphene electrodes Ma, H., Zhao, S., Daasbjerg, K., Jakobsen, R., Pu, S. & Hansen, H. C. B., Nov 2024, In: Chemical Engineering Journal. 500, 9 p., 156947. Hierarchical Superhydrophilic/Superaerophobic Ni3S2/VS2 Nanorod-Based Bifunctional Electrocatalyst Supported on Nickel Foam for Overall Urea Electrolysis Huang, Y., Xu, H., Wang, Y., Xing, Z., Fang, R., Lai, H., Qian, M., Dong, M., Carraro, M., Skrydstrup, T., Daasbjerg, K. & Xin, Z., 7 Oct 2024, In: Inorganic Chemistry. 63, 40, p. 19002-19010 9 p. Hollow CoFe Oxide Prisms for Cross-Dehydrogenative Coupling Reactions of 1,2,3,4-Tetrahydroisoquinolines under Mild Conditions Xin, Z., Kou, J., Xu, H., Liu, Q., Carraro, M., Dong, M., Daasbjerg, K., Skrydstrup, T. & Huang, Y., 30 Sept 2024, In: Inorganic Chemistry. 63, 39, p. 18489-18494 6 p. Mesopore-Augmented Electrochemical CO2 Reduction on Nitrogen-Doped Carbon Han, X., Zhang, T., Biset-Peiró, M., Roldan, A., Ceccato, M., Lock, N., Pedersen, S. U., Morante, J. R., Arbiol, J. & Daasbjerg, K., 22 Nov 2024, (E-pub / Early view) In: Small (Weinheim an der Bergstrasse, Germany). 2406883, 10 p., 2406883. NHC-CDI Ligands Boost Multicarbon Production in Electrocatalytic CO2 Reduction by Increasing Accumulated Charged Intermediates and Promoting *CO Dimerization on Cu Kolding, K. N., Bretlau, M., Zhao, S., Ceccato, M., Torbensen, K., Daasbjerg, K. & Rosas-Hernández, A., May 2024, In: Journal of the American Chemical Society. 146, 19, p. 13034-13045 12 p. Open frame-like Co-Fe oxides superstructures for highly efficient cross-dehydrogenative coupling reaction of N-phenyltetrahydroisoquinoline under mild conditions Xin, Z., Kou, J., Luo, M., Liu, Q., Carraro, M., Dong, M., Daasbjerg, K., Skrydstrup, T. & Huang, Y., Dec 2024, In: Inorganic Chemistry Communications. 170, 2, 7 p., 113352. A MOF-Based Spatial-Separation Layer to Enable a Uniform Favorable Microenvironment for Electrochemical CO2 Reduction Han, X., Zhang, T., Biset-Peiró, M., Zhao, S., Murcia Lopez, S., Daasbjerg, K., Morante, J. R., Li, J. & Arbiol, J., Aug 2023, In: Small Structures. 4, 8, 8 p., 2200388. A Monolayer Carbon Nitride on Au(111) with a High Density of Single Co Sites Gammelgaard, J. J., Sun, Z., Vestergaard, A. K., Zhao, S., Li, Z., Lock, N., Daasbjerg, K., Bagger, A., Rossmeisl, J. & Lauritsen, J. V., Sept 2023, In: ACS Nano. 17, 17, p. 17489-17498 10 p. Exploring the Parameters Controlling Product Selectivity in Electrochemical CO2 Reduction in Competition with Hydrogen Evolution Employing Manganese Bipyridine Complexes Hong, W., Luthra, M., Jakobsen, J. B., Madsen, M. R., Castro, A. C., Hammershøj, H. C. D., Pedersen, S. U., Balcells, D., Skrydstrup, T., Daasbjerg, K. & Nova, A., Mar 2023, In: ACS Catalysis. 13, 5, p. 3109-3119 11 p. Interfacial Engineering of PVDF‐TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applications Abdolmaleki, H., Astri Bjørnetun Haugen, A., Buhl, K. B., Daasbjerg, K. & Agarwala, S., 24 Feb 2023, In: Advanced Science. 10, 6, 2205942. Rational Design of Heterogeneous Dual-Atom Catalysts for CO2 Electroreduction Reactions Jafarzadeh, M. & Daasbjerg, K., Jun 2023, In: ACS Applied Energy Materials. 6, 13, p. 6851–6882 32 p. Steering carbon dioxide reduction toward C-C coupling using copper electrodes modified with porous molecular films Zhao, S., Christensen, O., Sun, Z., Liang, H., Bagger, A., Torbensen, K., Nazari, P., Lauritsen, J. V., Pedersen, S. U., Rossmeisl, J. & Daasbjerg, K., Feb 2023, In: Nature Communications. 14, 1, 844. Surface-Initiated Controlled Radical Polymerization: Going beyond Laboratory Scale Pagh Nikolajsen, J., Vogtmann Thinnesen, L., Karabiber, O. A., Daasbjerg, K., Pedersen, S. U., Kongsfelt, M. & Lillethorup, M., May 2023, In: ACS Applied Polymer Materials. 5, 5, p. 3534-3541 8 p. Can the CO2Reduction Reaction Be Improved on Cu: Selectivity and Intrinsic Activity of Functionalized Cu Surfaces Christensen, O., Zhao, S., Sun, Z., Bagger, A., Lauritsen, J. V., Pedersen, S. U., Daasbjerg, K. & Rossmeisl, J., Dec 2022, In: ACS Catalysis. 12, 24, p. 15737-15749 13 p. Challenges and Prospects in the Catalytic Conversion of Carbon Dioxide to Formaldehyde Zhao, S., Liang, H. Q., Hu, X. M., Li, S. & Daasbjerg, K., Nov 2022, In: Angewandte Chemie - International Edition. 61, 46, 15 p., e202204008. Electrocatalytic Depolymerization of Self-Immolative Poly(Dithiothreitol) Derivatives Hansen-Felby, M., Pedersen, S. U. & Daasbjerg, K., Oct 2022, In: Molecules. 27, 19, 16 p., 6292. High-pressure synthesis of CO and syngas from CO2 reduction using Ni-N-doped porous carbon electrocatalyst Proietto, F., Li, S., Loria, A., Hu, X.-M., Galia, A., Ceccato, M., Daasbjerg, K. & Scialdone, O., Feb 2022, In: Chemical Engineering Journal. 429, 10 p., 132251. p-Block Indium Single-Atom Catalyst with Low-Coordinated In-N Motif for Enhanced Electrochemical CO2 Reduction Li, S., Lu, X., Zhao, S., Ceccato, M., Hu, X.-M., Roldan, A., Liu, M. & Daasbjerg, K., Jun 2022, In: ACS Catalysis. 12, 12, p. 7386-7395 10 p. Postfunctionalization of Self-Immolative Poly(dithiothreitol) Using Steglich Esterification Hansen-Felby, M., Henriksen, M. L., Pedersen, S. U. & Daasbjerg, K., 12 Jul 2022, In: Macromolecules. 55, 13, p. 5788-5794 7 p. Synthesis and depolymerization of self-immolative poly(disulfide)s with saturated aliphatic backbones Hansen-Felby, M., Sommerfeldt, A., Henriksen, M. L., Pedersen, S. U. & Daasbjerg, K., Jan 2022, In: Polymer Chemistry. 13, 1, p. 85-90 6 p. A novel approach toward attachment of graphene oxide on copper using electrochemical grafting of an organic interlayer with enhanced corrosion performance Adel-Mehraban, F., Raeissi, K., Karimzadeh, F., Pedersen, S. U., Salehzadeh, H. & Daasbjerg, K., May 2021, In: Progress in Organic Coatings. 154, 11 p., 106185. Are Amines the Holy Grail for Facilitating CO2 Reduction? Jakobsen, J. B., Rønne, M. H., Daasbjerg, K. & Skrydstrup, T., 19 Apr 2021, In: Angewandte Chemie International Edition. 60, 17, p. 9174-9179 6 p. Chapter 2: Homogeneous Electrochemical Reduction of CO2. From Homogeneous to Supported Systems Costentin, C., Daasbjerg, K. & Robert, M., 2021, Carbon Dioxide Electrochemistry: Homogeneous and Heterogeneous Catalysis. Robert, M., Costentin, C. & Daasbjerg, K. (eds.). 28 ed. Royal Society of Chemistry, p. 67-97 31 p. (RSC Energy and Environment Series; No. 28, Vol. 2021-January). Dual-Responsive Material Based on Catechol Modified Self Immolative Poly(Disulfide) Backbones Agergaard, A. H., Sommerfeldt, A., Pedersen, S. U., Birkedal, H. & Daasbjerg, K., 20 Sept 2021, In: Angewandte Chemie. 60, 39, p. 21543-21549 7 p. Highly Scalable Conversion of Blood Protoporphyrin to Efficient Electrocatalyst for CO 2-to-CO Conversion Miola, M., Li, S., Hu, X.-M., Ceccato, M., Surkus, A.-E., Welter, E., Pedersen, S. U., Junge, H., Skrydstrup, T., Beller, M. & Daasbjerg, K., 23 Jun 2021, In: Advanced Materials Interfaces. 8, 12, 9 p., 2100067. Hydrophobic Copper Interfaces Boost Electroreduction of Carbon Dioxide to Ethylene in Water Liang, H. Q., Zhao, S., Hu, X. M., Ceccato, M., Skrydstrup, T. & Daasbjerg, K., Jan 2021, In: ACS Catalysis. 11, 2, p. 958-966 9 p. Incorporation of nickel single atoms into carbon paper as self-standing electrocatalyst for CO2reduction Li, S., Ceccato, M., Lu, X., Frank, S., Lock, N., Roldan, A., Hu, X. M., Skrydstrup, T. & Daasbjerg, K., Jan 2021, In: Journal of Materials Chemistry A. 9, 3, p. 1583-1592 10 p. Low-Valence Znδ+ (0<δ<2) Single-Atom Material as Highly Efficient Electrocatalyst for CO2 Reduction Li, S., Zhao, S., Lu, X., Ceccato, M., Hu, X.-M., Roldan, A., Catalano, J., Liu, M., Skrydstrup, T. & Daasbjerg, K., 11 Oct 2021, In: Angewandte Chemie International Edition. 60, 42, p. 22826-22832 7 p. Mechanistic Elucidation of Dimer Formation and Strategies for Its Suppression in Electrochemical Reduction of Fac-Mn(bpy)(CO)3Br Rønne, M. H., Madsen, M. R., Skrydstrup, T., Pedersen, S. U. & Daasbjerg, K., Jun 2021, In: ChemElectroChem. 8, 11, p. 2108-2114 7 p. Mode I debonding under large deformation conditions including notes on cleavage-peeling transition Heide-Jørgensen, S., Budzik, M. K., Buhl, K. B., Hinge, M., Pedersen, S. U., Daasbjerg, K. & Kongsfelt, M., Jan 2021, In: Engineering Fracture Mechanics. 241, 20 p., 107413. Promoting Selective Generation of Formic Acid from CO2 Using Mn(bpy)(CO)3Br as Electrocatalyst and Triethylamine/Isopropanol as Additives Madsen, M. R., Rønne, M. H., Heuschen, M., Golo, D., Ahlquist, M. S. G., Skrydstrup, T., Pedersen, S. U. & Daasbjerg, K., Dec 2021, In: Journal of the American Chemical Society. 143, 48, p. 20491-20500 10 p. Spectroscopic Evidence for a Covalent Sigma Au-C Bond on Au Surfaces Using C-13 Isotope Labeling Li, H., Kopiec, G., Mueller, F., Nyssen, F., Shimizu, K., Ceccato, M., Daasbjerg, K. & Plumere, N., 22 Mar 2021, In: Journal of the American Chemical Society Au. 1, 3, p. 362-368 7 p. Achieving Near-Unity CO Selectivity for CO2 Electroreduction on an Iron-Decorated Carbon Material Hu, X. M., Mendoza, D., Madsen, M. R., Joulié, D., Lassalle-Kaiser, B., Robert, M., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K., Dec 2020, In: ChemSusChem (Print). 13, 23, p. 6360-6369 10 p. Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere Madsen, M. R., Jakobsen, J. B., Rønne, M. H., Liang, H., Hammershøj, H. C. D., Nørby, P., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K., May 2020, In: Organometallics. 39, 9, p. 1480-1490 Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layers Buhl, K. B., Agergaard, A. H., Møller, R., Kongsfelt, M., Heide-Jørgensen, S., Budzik, M. K., Hinge, M., Pedersen, S. U. & Daasbjerg, K., 12 Jun 2020, In: ACS Applied Polymer Materials. 2, 6, p. 2380-2388 9 p. Ligand-Controlled Product Selectivity in Electrochemical Carbon Dioxide Reduction Using Manganese Bipyridine Catalysts Rønne, M. H., Cho, D., Madsen, M. R., Jakobsen, J. B., Eom, S., Escoudé, É., Hammershøj, H. C. D., Nielsen, D. U., Pedersen, S. U., Baik, M. H., Skrydstrup, T. & Daasbjerg, K., 4 Mar 2020, In: Journal of the American Chemical Society. 142, 9, p. 4265-4275 11 p. Main element chemistry enables gas-cylinder-free hydroformylations Pedersen, S. K., Gudmundsson, H. G., Nielsen, D. U., Donslund, B. S., Hammershøj, H. C. D., Daasbjerg, K. & Skrydstrup, T., Oct 2020, In: Nature Catalysis. 3, 10, p. 843-850 8 p. Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrode Abbasi, A. R., Yousefshahi, M. & Daasbjerg, K., 2020, In: Journal of Inorganic and Organometallic Polymers and Materials. 30, 6, p. 2027-2038 12 p. Polymer brush coating and adhesion technology at scale Buhl, K. B., Agergaard, A. H., Lillethorup, M., Nikolajsen, J. P., Pedersen, S. U. & Daasbjerg, K., 2020, In: Polymers. 12, 7, 15 p., 1475. Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO2 Reduction to Formate Lamagni, P., Miola, M., Catalano, J., Hvid, M. S., Mamakhel, M. A. H., Christensen, M., Madsen, M. R., Jeppesen, H. S., Hu, X. M., Daasbjerg, K., Skrydstrup, T. & Lock, N., Apr 2020, In: Advanced Functional Materials. 30, 16, 11 p., 1910408. Robust tuning metal/carbon heterointerfaces via ketonic oxygen enables hydrogen evolution reaction outperforming Pt/C Yu, J., Yang, Y., Jia, R., Daasbjerg, K., Wang, J., Carraro, M., Xin, Z., Huang, Y. & Skrydstrup, T., Nov 2020, In: Applied Surface Science. 529, 8 p., 147080. Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachments Agergaard, A. H., Pedersen, S. U., Birkedal, H. & Daasbjerg, K., 21 Sept 2020, In: Polymer Chemistry. 11, 35, p. 5572-5577 6 p. Stoichiometric Studies on the Carbonylative Trifluoromethylation of Aryl Pd(II) Complexes using TMSCF3 as the Trifluoromethyl Source Domino, K., Johansen, M. B., Daasbjerg, K. & Skrydstrup, T., 9 Mar 2020, In: Organometallics. 39, 5, p. 688-697 10 p. Synthesis and Closed-Loop Recycling of Self-Immolative Poly(dithiothreitol) Pal, S., Sommerfeldt, A., Davidsen, M. B., Hinge, M., Pedersen, S. U. & Daasbjerg, K., Jun 2020, In: Macromolecules. 53, 12, p. 4685-4691 7 p. Understanding the Enhanced Catalytic CO2 Reduction upon Adhering Cobalt Porphyrin to Carbon Nanotubes and the Inverse Loading Effect Chen, X., Hu, X. M., Daasbjerg, K. & Ahlquist, M. S. G., May 2020, In: Organometallics. 39, 9, p. 1634-1641 8 p. Access to β-Ketonitriles through Nickel-Catalyzed Carbonylative Coupling of α-Bromonitriles with Alkylzinc Reagents Donslund, A. S., Neumann, K. T., Corneliussen, N. P., Grove, E. K., Herbstritt, D., Daasbjerg, K. & Skrydstrup, T., Jul 2019, In: Chemistry - A European Journal. 25, 42, p. 9856-9860 5 p. Carbon Isotope Labeling Strategy for β-Amino Acid Derivatives via Carbonylation of Azanickellacycles Ravn, A. K., Vilstrup, M. B. T., Nørby, P., Nielsen, D. U., Daasbjerg, K. & Skrydstrup, T., 2019, In: Journal of the American Chemical Society. 141, 30, p. 11821-11826 6 p. Erratum to: Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals (Nature Catalysis, (2018), 1, 4, (244-254), 10.1038/s41929-018-0051-3) Nielsen, D. U., Hu, X. M., Daasbjerg, K. & Skrydstrup, T., 1 Jan 2019, In: Nature Catalysis. 2, 1, p. 95 1 p. Evaluation of Surface-initiated Polymer brush as Anti-scaling Coating for Plate Heat Exchangers Friis, J. E., Subbiahdoss, G., Gerved, G., Holm, A. H., Santos, O., Blichfeld, A. B., Moghaddam, S. Z., Thormann, E., Daasbjerg, K., Iruthayaraj, J. & Meyer, R. L., Nov 2019, In: Progress in Organic Coatings. 136, 105196. Hydrosilane-Modified Poly(2-Hydroxyethyl Methacrylate) Brush as a Nanoadhesive for Efficient Silicone Bonding Nielsen, S., Olsen, M. H., Kongsfelt, M., Pedersen, S. U. & Daasbjerg, K., 31 Jul 2019, In: ACS Omega. 4, 7, p. 12130-12135 6 p. Molecular catalyst converts carbon dioxide to methanol Hu, X. M. & Daasbjerg, K., 2019, In: Nature. 575, 7784, p. 598-599 2 p. Supported molecular catalysts for the heterogeneous CO2 electroreduction Hu, X. M., Pedersen, S. U. & Daasbjerg, K., Jun 2019, In: Current Opinion in Electrochemistry. 15, p. 148-154 7 p. Two-phase bipolar electrografting Madsen, M. R., Koefoed, L., Jensen, H., Daasbjerg, K. & Pedersen, S. U., Sept 2019, In: Electrochimica Acta. 317, p. 61-69 9 p.