鲍宗必
教授
个人简介
现任生物质化工教育部重点实验室副主任、浙江大学制药工程研究所所长、浙江大学衢州研究院电子化学品研究所所长。国家杰出青年科学基金获得者(2022年)、国家优秀青年科学基金获得者(2017年)、浙江省杰出青年科学基金获得者(2016年),浙江省“计划”青年拔尖人才。2003年毕业浙江大学材料与化工学院,获制药工程学士学位,2008年获浙江大学化学工程博士学位,2009-2011于浙江大学环境科学与工程博士后流动站、美国New Mexico State University从事博士后研究,2011年留校任教,2015-2016年受国家留学基金委及浙江大学“青年骨干教师计划”共同资助赴美国University of Texas at San Antonio访学,2018年晋升教授。主要从事化工分离技术研究,在Science、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Energ. Environ. Sci.、AIChE J.等期刊发表论文150余篇,获中国授权发明专利60余件、美国授权专利3件。承担国家自然科学基金区域创新发展联合基金重点项目、重点研发计划项目课题、浙江省自然科学基金委重点项目等20余项,获国家技术发明奖二等奖、浙江省科技进步一等奖、中国石化联合会科技进步二等奖、侯德榜化工科学技术青年奖、J. Colloid Interf. Sci.期刊“Top Cited Author”等荣誉。兼任中国化工学会超临界流体专委会秘书长、中国化工学会电子化学品专委会委员、《Separation and Purification Technology》副主编、《浙大学报(英文版)》青年编委、《化工进展》编委。 教育及工作经历 1999.09-2003.06 浙江大学,制药工程,本科 2003.09-2008.12 浙江大学,化学工程,硕博连读 2009.01-2009.10 浙江大学,环境科学与工程学科流动站,学科博士后 2009.11-2010.10 美国New Mexico State University,博士后 2015.03-2016.03 美国The University of Texas at San Antonio,访问学者 2011.03-2011.12 浙江大学化工学院,讲师 2011.12-2018.12 浙江大学化工学院,副教授 2018.05至今 浙江大学制药工程研究所,副所长 2018.12至今 浙江大学化工学院,教授 2020.10至今 浙江大学生物质化工教育部重点实验室副主任 获得荣誉 侯德榜化工科学技术青年奖(2019年) 浙江省“计划”青年拔尖人才(2019年) 浙江省151人才二层次(2018年) 浙江大学化工学院“学生最喜爱的十佳教学名师”(2018年) 国家优秀青年科学基金获得者(2017年) 浙江省杰出青年科学基金获得者(2016年) 浙江省151人才三层次(2015年) 浙江大学求是青年学者(2013年) 爱思唯尔Journal of Colloid and Interface Science期刊“2010年度Top Cited Author”
研究领域
金属有机框架材料、多孔炭材料 吸附分离工程 天然产物分离纯化 超临界流体技术
金属有机框架材料、多孔炭材料设计制备与应用 吸附分离工程(变压吸附、模拟移动床色谱等) 天然产物、低碳烃、电子特气、湿电子化学品的分离纯化 超临界流体、离子液体等绿色分离技术
学术兼职
国际期刊Separation and Purification Technology (IF=9.136)副主编 (2022.6至今) 美国New Mexico State University客座研究员(2013-2014) 中国化工学会超临界流体专业委员会秘书长 中国化工学会过程强化专业委员会青年委员 中国化工学会会刊《化工进展》第10、11届编委会委员 浙江省药学会制药工程专业委员会委员 Nat. Commun./J. Am. Chem. Soc./AIChE J./Chem. Commun./J. Mater. Chem. A/Small等专业期刊审稿人
近期论文
Li, L.; Guo, L.; Olson, D. H.; Xian, S.; Zhang, Z.; Yang, Q.; Wu, K.; Yang, Y.; Bao, Z.; Ren, Q.; Li, J. Discrimination of Xylene Isomers in a Stacked Coordination Polymer. Science 2022, 377 (6603), 335–339. https://doi.org/10.1126/science.abj7659. Zheng, F.; Guo, L.; Chen, R.; Chen, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Ren, Q.; Bao, Z. Shell‐like Xenon Nano‐Traps within Angular Anion‐Pillared Layered Porous Materials for Boosting Xe/Kr Separation. Angewandte Chemie 2022. https://doi.org/10.1002/ange.202116686. Liu, Y.; Wu, H.; Guo, L.; Zhou, W.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Cover Picture: Hydrogen‐Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton (Angew. Chem. Int. Ed. 11/2022). Angew Chem Int Ed 2022, 61 (11). https://doi.org/10.1002/anie.202202166. Liu, Y.; Dai, J.; Guo, L.; Zhang, Z.; Yang, Y.; Yang, Q.; Ren, Q.; Bao, Z. Porous Hydrogen-Bonded Frameworks Assembled from Metal-Nucleobase Entities for Xe/Kr Separation. CCS Chem 2022, 4 (1), 381–388. https://doi.org/10.31635/ccschem.021.202100824. Liu, C.; Li, W.; Liu, Y.; Wang, H.; Yu, B.; Bao, Z.; Jiang, J. Porous Organic Cages for Efficient Gas Selective Separation and Iodine Capture. Chemical Engineering Journal 2022, 428, 131129. https://doi.org/10.1016/j.cej.2021.131129. Zheng, F.; Chen, L.; Chen, R.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Ren, Q.; Bao, Z. A Robust Two–Dimensional Layered Metal–Organic Framework for Efficient Separation of Methane from Nitrogen. Separation and Purification Technology 2022, 281, 119911. https://doi.org/10.1016/j.seppur.2021.119911. Jiang, S.; Guo, L.; Chen, L.; Song, C.; Liu, B.; Yang, Q.; Zhang, Z.; Yang, Y.; Ren, Q.; Bao, Z. A Strongly Hydrophobic Ethane-Selective Metal-Organic Framework for Efficient Ethane/Ethylene Separation. Chemical Engineering Journal 2022, 136152. https://doi.org/10.1016/j.cej.2022.136152. Yu, Q.; Guo, L.; Lai, D.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. A Pore-Engineered Metal-Organic Framework with Mixed Ligands Enabling Highly Efficient Separation of Hexane Isomers for Gasoline Upgrading. Separation and Purification Technology 2021, 268, 118646. https://doi.org/10.1016/j.seppur.2021.118646. Wu, K.; Guo, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Shaping of Gallate-Based Metal-Organic Frameworks for Adsorption Separation of Ethylene from Acetylene and Ethane. Journal of Colloid and Interface Science 2021, 581, 177–184. https://doi.org/10.1016/j.jcis.2020.07.111. Liu, Y.; Dai, J.; Zhang, Z.; Yang, Y.; Yang, Q.; Ren, Q.; Bao, Z. Crystal Structure Transformation in Hydrogen‐bonded Organic Frameworks via Ion Exchange. Chem. Asian J. 2021, 16 (23), 3978–3984. https://doi.org/10.1002/asia.202101151. Jiang, S.; Li, L.; Guo, L.; Song, C.; Yang, Q.; Zhang, Z.; Yang, Y.; Ren, Q.; Bao, Z. A Robust Ethane-Trapping Metal-Organic Framework for Efficient Purification of Ethylene. Sci. China Chem. 2021, 64 (4), 666–672. https://doi.org/10.1007/s11426-020-9929-8. Chen, F.; Lai, D.; Guo, L.; Wang, J.; Zhang, P.; Wu, K.; Zhang, Z.; Yang, Q.; Yang, Y.; Chen, B.; Ren, Q.; Bao, Z. Deep Desulfurization with Record SO2 Adsorption on the Metal–Organic Frameworks. J. Am. Chem. Soc. 2021, 143 (24), 9040–9047. https://doi.org/10.1021/jacs.1c02176. Chen, F.; Ding, J.; Guo, K.; Yang, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; He, Y.; Ren, Q. CoNi Alloy Nanoparticles Embedded in Metal–Organic Framework‐Derived Carbon for the Highly Efficient Separation of Xenon and Krypton via a Charge‐Transfer Effect. Angew. Chem. Int. Ed. 2021, 60 (5), 2431–2438. https://doi.org/10.1002/anie.202011778. Yu, X.; Wang, Y.; Yang, Q.; Zhang, Z.; Ren, Q.; Bao, Z.; Yang, Y. De Novo Synthesis of Microspheical Cellulose 3,5-Dichlorophenylcarbamates: An Organic-Inorganic Hybrid Chiral Stationary Phase for Enantiospearation. Separation and Purification Technology 2020, 238, 116480. https://doi.org/10.1016/j.seppur.2019.116480. Wang, Q.; Ke, T.; Yang, L.; Zhang, Z.; Cui, X.; Bao, Z.; Ren, Q.; Yang, Q.; Xing, H. Titelbild: Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving (Angew. Chem. 9/2020). Angew. Chem. 2020, 132 (9), 3365–3365. https://doi.org/10.1002/ange.202000349. Shen, J.; He, X.; Ke, T.; Krishna, R.; van Baten, J. M.; Chen, R.; Bao, Z.; Xing, H.; Dincǎ, M.; Zhang, Z.; Yang, Q.; Ren, Q. Simultaneous Interlayer and Intralayer Space Control in Two-Dimensional Metal−organic Frameworks for Acetylene/Ethylene Separation. Nat Commun 2020, 11 (1), 6259. https://doi.org/10.1038/s41467-020-20101-7. Qi, L.; Chen, J.; Zhang, B.; Nie, R.; Qi, Z.; Kobayashi, T.; Bao, Z.; Yang, Q.; Ren, Q.; Sun, Q.; Zhang, Z.; Huang, W. Deciphering a Reaction Network for the Switchable Production of Tetrahydroquinoline or Quinoline with MOF-Supported Pd Tandem Catalysts. ACS Catal. 2020, 10 (10), 5707–5714. https://doi.org/10.1021/acscatal.0c00899. Li, Z.; Li, L.; Guo, L.; Wang, J.; Yang, Q.; Zhang, Z.; Yang, Y.; Bao, Z.; Ren, Q. Gallate-Based Metal–Organic Frameworks for Highly Efficient Removal of Trace Propyne from Propylene. Ind. Eng. Chem. Res. 2020, 59 (30), 13716–13723. https://doi.org/10.1021/acs.iecr.0c01726. Li, L.; Guo, L.; Zheng, F.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Calcium-Based Metal–Organic Framework for Simultaneous Capture of Trace Propyne and Propadiene from Propylene. ACS Appl. Mater. Interfaces 2020, 12 (14), 17147–17154. https://doi.org/10.1021/acsami.0c03139. Ke, T.; Wang, Q.; Shen, J.; Zhou, J.; Bao, Z.; Yang, Q.; Ren, Q. Molecular Sieving of C 2 ‐C 3 Alkene from Alkyne with Tuned Threshold Pressure in Robust Layered Metal–Organic Frameworks. Angew. Chem. 2020, 132 (31), 12825–12830. https://doi.org/10.1002/ange.202003421. Dai, J.; Xie, D.; Liu, Y.; Zhang, Z.; Yang, Y.; Yang, Q.; Ren, Q.; Bao, Z. Supramolecular Metal–Organic Framework for CO 2 /CH 4 and CO 2 /N 2 Separation. Ind. Eng. Chem. Res. 2020, 59 (16), 7866–7874. https://doi.org/10.1021/acs.iecr.0c00447. Chen, J.; Wang, J.; Guo, L.; Li, L.; Yang, Q.; Zhang, Z.; Yang, Y.; Bao, Z.; Ren, Q. Adsorptive Separation of Geometric Isomers of 2-Butene on Gallate-Based Metal–Organic Frameworks. ACS Appl. Mater. Interfaces 2020, 12 (8), 9609–9616. https://doi.org/10.1021/acsami.9b20092. Chen, F.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q. Microporous Carbon Adsorbents Prepared by Activating Reagent-Free Pyrolysis for Upgrading Low-Quality Natural Gas. ACS Sustainable Chem. Eng. 2020, 8 (2), 977–985. https://doi.org/10.1021/acssuschemeng.9b05627. Zhu, J.; Chen, F.; Zhang, Z.; Li, M.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q. M-Gallate (M = Ni, Co) Metal–Organic Framework-Derived Ni/C and Bimetallic Ni–Co/C Catalysts for Lignin Conversion into Monophenols. ACS Sustainable Chem. Eng. 2019, 7 (15), 12955–12963. https://doi.org/10.1021/acssuschemeng.9b02005. Zheng, F.; Guo, L.; Gao, B.; Li, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Ren, Q.; Bao, Z. Engineering the Pore Size of Pillared-Layer Coordination Polymers Enables Highly Efficient Adsorption Separation of Acetylene from Ethylene. ACS Appl. Mater. Interfaces 2019, 11 (31), 28197–28204. https://doi.org/10.1021/acsami.9b09231. Wang, J.; Li, L.; Guo, L.; Zhao, Y.; Xie, D.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q. Adsorptive Separation of Acetylene from Ethylene in Isostructural Gallate‐Based Metal–Organic Frameworks. Chem. Eur. J. 2019, 25 (68), 15516–15524. https://doi.org/10.1002/chem.201903952. Li, L.; Wang, J.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Bao, Z.; Ren, Q. Inverse Adsorption Separation of CO 2 /C 2 H 2 Mixture in Cyclodextrin-Based Metal–Organic Frameworks. ACS Appl. Mater. Interfaces 2019, 11 (2), 2543–2550. https://doi.org/10.1021/acsami.8b19590. Li, L.; Guo, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q.; Li, J. A Robust Squarate-Based Metal–Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton. J. Am. Chem. Soc. 2019, 141 (23), 9358–9364. https://doi.org/10.1021/jacs.9b03422. Li, L.; Guo, L.; Pu, S.; Wang, J.; Yang, Q.; Zhang, Z.; Yang, Y.; Ren, Q.; Alnemrat, S.; Bao, Z. A Calcium-Based Microporous Metal-Organic Framework for Efficient Adsorption Separation of Light Hydrocarbons. Chemical Engineering Journal 2019, 358, 446–455. https://doi.org/10.1016/j.cej.2018.10.034. Gao, B.; Huang, M.; Zhang, Z.; Yang, Q.; Su, B.; Yang, Y.; Ren, Q.; Bao, Z. Hybridization of Metal–Organic Framework and Monodisperse Spherical Silica for Chromatographic Separation of Xylene Isomers. Chinese Journal of Chemical Engineering 2019, 27 (4), 818–826. https://doi.org/10.1016/j.cjche.2018.06.016. Zhao, Y.; Wang, J.; Bao, Z.; Xing, H.; Zhang, Z.; Su, B.; Yang, Q.; Yang, Y.; Ren, Q. Adsorption Separation of Acetylene and Ethylene in a Highly Thermostable Microporous Metal-Organic Framework. Separation and Purification Technology 2018, 195, 238–243. https://doi.org/10.1016/j.seppur.2017.11.044. Yang, L.; Cui, X.; Zhang, Z.; Yang, Q.; Bao, Z.; Ren, Q.; Xing, H. An Asymmetric Anion‐Pillared Metal–Organic Framework as a Multisite Adsorbent Enables Simultaneous Removal of Propyne and Propadiene from Propylene. Angew. Chem. 2018, 130 (40), 13329–13333. https://doi.org/10.1002/ange.201807652. Yang, L.; Cui, X.; Yang, Q.; Qian, S.; Wu, H.; Bao, Z.; Zhang, Z.; Ren, Q.; Zhou, W.; Chen, B.; Xing, H. Gas Separation: A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials (Adv. Mater. 10/2018). Adv. Mater. 2018, 30 (10), 1870068. https://doi.org/10.1002/adma.201870068. Pu, S.; Wang, J.; Li, L.; Zhang, Z.; Bao, Z.; Yang, Q.; Yang, Y.; Xing, H.; Ren, Q. Performance Comparison of Metal–Organic Framework Extrudates and Commercial Zeolite for Ethylene/Ethane Separation. Ind. Eng. Chem. Res. 2018, 57 (5), 1645–1654. https://doi.org/10.1021/acs.iecr.7b04391. Li, L.; Yang, L.; Wang, J.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Highly Efficient Separation of Methane from Nitrogen on a Squarate-Based Metal-Organic Framework. AIChE J 2018, 64 (10), 3681–3689. https://doi.org/10.1002/aic.16335. Bao, Z.; Xie, D.; Chang, G.; Wu, H.; Li, L.; Zhou, W.; Wang, H.; Zhang, Z.; Xing, H.; Yang, Q.; Zaworotko, M. J.; Ren, Q.; Chen, B. Fine Tuning and Specific Binding Sites with a Porous Hydrogen-Bonded Metal-Complex Framework for Gas Selective Separations. J. Am. Chem. Soc. 2018, 140 (13), 4596–4603. https://doi.org/10.1021/jacs.7b13706. Bao, Z.; Wang, J.; Zhang, Z.; Xing, H.; Yang, Q.; Yang, Y.; Wu, H.; Krishna, R.; Zhou, W.; Chen, B.; Ren, Q. Molecular Sieving of Ethane from Ethylene through the Molecular Cross‐Section Size Differentiation in Gallate‐based Metal–Organic Frameworks. Angew. Chem. 2018, 130 (49), 16252–16257. https://doi.org/10.1002/ange.201808716. Zhang, X.; Wang, J.; Chen, S.; Bao, Z.; Xing, H.; Zhang, Z.; Su, B.; Yang, Q.; Yang, Y.; Ren, Q. A Spherical N-Methyl-d-Glucamine-Based Hybrid Adsorbent for Highly Efficient Adsorption of Boric Acid from Water. Separation and Purification Technology 2017, 172, 43–50. https://doi.org/10.1016/j.seppur.2016.08.002. Yang, W.; Wang, J.; Wang, H.; Bao, Z.; Zhao, J. C.-G.; Chen, B. Highly Interpenetrated Robust Microporous Hydrogen-Bonded Organic Framework for Gas Separation. Crystal Growth & Design 2017, 17 (11), 6132–6137. https://doi.org/10.1021/acs.cgd.7b01322. Wang, J.; Xie, D.; Zhang, Z.; Yang, Q.; Xing, H.; Yang, Y.; Ren, Q.; Bao, Z. Efficient Adsorption Separation of Acetylene and Ethylene via Supported Ionic Liquid on Metal‐organic Framework. AIChE J. 2017, 63 (6), 2165–2175. https://doi.org/10.1002/aic.15561. Wang, H.; Bao, Z.; Wu, H.; Lin, R.-B.; Zhou, W.; Hu, T.-L.; Li, B.; Zhao, J. C.-G.; Chen, B. Two Solvent-Induced Porous Hydrogen-Bonded Organic Frameworks: Solvent Effects on Structures and Functionalities. Chem. Commun. 2017, 53 (81), 11150–11153. https://doi.org/10.1039/C7CC06187K. Wang, J.; Bao, Z.; Xing, H.; Su, B.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Chen, B. Incorporation of N -Methyl- d -Glucamine Functionalized Oligomer into MIL-101(Cr) for Highly Efficient Removal of Boric Acid from Water. Chem. Eur. J. 2016, 22 (43), 15290–15297. https://doi.org/10.1002/chem.201602599. Su, Y.; Chang, G.; Zhang, Z.; Xing, H.; Su, B.; Yang, Q.; Ren, Q.; Yang, Y.; Bao, Z. Catalytic Dehydration of Glucose to 5-Hydroxymethylfurfural with a Bifunctional Metal-Organic Framework. AIChE J. 2016, 62 (12), 4403–4417. https://doi.org/10.1002/aic.15356. Jin, W.; Yang, Q.; Huang, B.; Bao, Z.; Su, B.; Ren, Q.; Yang, Y.; Xing, H. Enhanced Solubilization and Extraction of Hydrophobic Bioactive Compounds Using Water/Ionic Liquid Mixtures. Green Chem. 2016, 18 (12), 3549–3557. https://doi.org/10.1039/C6GC00584E. Cui, X.; Chen, K.; Xing, H.; Yang, Q.; Krishna, R.; Bao, Z.; Wu, H.; Zhou, W.; Dong, X.; Han, Y.; Li, B.; Ren, Q.; Zaworotko, M. J.; Chen, B. Pore Chemistry and Size Control in Hybrid Porous Materials for Acetylene Capture from Ethylene. Science 2016, 353 (6295), 141–144. https://doi.org/10.1126/science.aaf2458. Chang, G.; Li, B.; Wang, H.; Hu, T.; Bao, Z.; Chen, B. Control of Interpenetration in a Microporous Metal–Organic Framework for Significantly Enhanced C 2 H 2 /CO 2 Separation at Room Temperature. Chem. Commun. 2016, 52 (17), 3494–3496. https://doi.org/10.1039/C5CC10598F. Bao, Z.; Chang, G.; Xing, H.; Krishna, R.; Ren, Q.; Chen, B. Potential of Microporous Metal–Organic Frameworks for Separation of Hydrocarbon Mixtures. Energy Environ. Sci. 2016, 9 (12), 3612–3641. https://doi.org/10.1039/C6EE01886F.