段伟良 照片

段伟良

副研究员

所属大学: 中国科学院上海有机化学研究所

所属学院: 金属有机化学国家重点实验室

邮箱:
wlduan@sioc.ac.cn

研究领域

过渡金属催化惰性碳氢键活化的研究 不对称催化:包括手性配体的合成应用和不对称催化反应的研究

近期论文

Feng. J.-J.; Chen. X.-F.; Shi, M.; Duan, W.-L.* Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines J. Am. Chem. Soc. 2010, 132, 5562.

Duan, W.-L.; Imazaki, Y.; Shintani, R.*; Hayashi, T.* Asymmetric Construction of Chiral C–N Axes through Rhodium-Catalyzed 1,4-Addition. Tetrahedron 2007, 63, 8529.

Duan, W.-L.; Iwamura, H.; Shintani, R.*; Hayashi, T.* Chiral Phosphine–Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions. J. Am. Chem. Soc. 2007, 129, 2130.

Shintani, R.; Duan, W.-L.; Hayashi, T.* Rhodium-Catalyzed Asymmetric Construction of Quaternary Carbon Stereocenters: Ligand-Dependent Regiocontrol in the 1,4-Addition to Substituted Maleimides. J. Am. Chem. Soc. 2006, 128, 5628.

Shintani, R.; Duan, W.-L.; Nagano, T.; Okada, A.; Hayashi, T.* Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides. Angew. Chem., Int. Ed. 2005, 44, 4611.

Duan, W-L.; Shi, M.*; Rong, G.-B. Synthesis of Novel Axially Chiral Rh-NHC Complexes Derived from BINAM and Application in the Enantioselective Hydrosilylation of Methyl Ketones. Chem. Commun. 2003, 2916.