陈庆云 照片

陈庆云

研究员

所属大学: 中国科学院上海有机化学研究所

所属学院: 有机氟化学重点实验室

邮箱:
chenqy@mail.sioc.ac.cn

个人主页:
http://chenqingyun.fncm.ac.cn/intro/

个人简介

学习经历 1948.09 – 1952.07 北京大学化学系 学士  1956.09 – 1960.06 苏联科学院元素有机化合物研究所 副博士  工作经历 1960.10-1963.8 中国科学院化学研究所  1963.8 –至今 中国科学院上海有机所  1993.11 当选为中科院院士

研究领域

有机氟化学反应方法学 从事全氟和多氟磺酸化学,开展了二氟卡宾和三氟甲基化的研究。首次发现二氟卡宾可以在强酸性介质中产生;合成和发现了14种二氟卡宾新前体、发展了 8种高效的三氟甲基化试剂和体系,其中最具代表性和应用最广的是氟砜基二氟 乙酸甲酯(FSO2CF2COOMe),被称为“陈试剂”。并开展全氟卤代烷的单电子 转移反应的研究,不仅为有机氟化物的合成提供了多种有效途径,而且将当代有 机化学最重要理论之一的单电子转移反应引入并发展了氟化学。 含氟表面活性剂 环境友好型含氟表面活性剂的设计、合成和应用

近期论文

Li, L.; Huang, M.; Liu, C.; Xiao, J.-C.; Chen, Q.-Y.*; Guo, Y.*; Zhao, Z.-G. “2,2,2-Trifluoroethylation of styrenes with concomitant introduction of a hydroxyl group from molecular oxygen by photoredox catalysis activated by visible light,” Org. Lett . 2015, 17, 4714−4717. Han, E.-J.; Sun, Y.; Shen, Q.; Chen, Q.-Y.*; Guo, Y.*; Huang, Y.-G. “Cu-mediated 2,2,2-Trifluoroethylation of Terminal Alkynes using 1,1-Dichloro-2,2,2-trifluoroethane (HCFC-123),” Org. Chem. Front. 2015, 2, 1379−1387. Wu, H.; Xiao, Z.; Wu, J.; Guo, Y.; Xiao, J.-C.; Liu, C.*; Chen Q.-Y.* “Direct Trifluoromethylthiolation of Unactivated C(sp3)-H using Silver(I) Trifluoromethanethiolate and Potassium Persulfate,” Angew. Chem. Int. Ed. 2015, 54, 4070−4074. Huan, F.; Chen, Q.-Y.*; Guo, Y.* “Visible Light-Induced Photoredox Construction of Trifluoromethylated Quaternary Carbon Centers fromTrifluoromethylated Tertiary Bromides,”J. Org. Chem.2016, 81,7051−7063 Liu, Y.; Wu,H.; Guo, Y.; Xiao,J.-C.; Chen,Q.-Y.*; Liu, C.*“Trifluoromethylfluorosulfonylation of Unactivated Alkenes UsingReadily Available Ag(O2CCF2SO2F) and N-fluorobenzenesulfonimide,” Angew. Chem. Int. Ed. 2017, 56, 15432-15435. Guo, Y.*; Huang, M.-W.; Fu, X.-L.; Liu, C.; Chen, Q.-Y.*; Zhao, Z.-G.*; Zeng, B.-Z.; Chen, J. “Recent catalytic syntheses of trifluoromethylthio-containing organic compounds by transition metals, chiral organocatalysts, and photocatalysts,” Chin. Chem. Lett. 2017, 28, 719–728. (Chinese Chemical Letters Excellent Papers Award 2019) Wang,W.*; Guo, Y.*; Sun, K.; Wang, S.; Zhang, S.; Liu, C.; Chen, Q.-Y.* “Visible Light-Induced Radical Cyclization of Tertiary Bromides with Isonitriles To Construct Trifluoromethylated Quaternary Carbon Center,” J. Org. Chem. 2018, 83, 14588-14599. Xiao, Z.; Liu, Y.; Zheng, L.; Liu, C.*; Guo, Y.; Chen, Q.-Y.* Oxidative Radical Intermolecular Trifluoromethylthioarylation of Styrenes by Arenediazonium Salts and Copper(I) Trifluoromethylthiolate. J. Org. Chem. 2018, 83, 5836-5843. Chen, T.;Guo, Y.*; Sun, K.; Wu, L.-Z.; Liu, W.-Q.; Liu, C.; Huang, Y.*; Chen, Q.-Y.* “Photoinduced hydroxylperfluoroalkylation ofstyrenes,” Org. Chem. Front. 2018, 5, 1045-1048. Zhao, S.; Guo, Y.*, Han, E.-J.; Luo, J.; Liu, H.-M.*; Liu, C.; Xie, W.; Zhang, W.; Wang, M. “Copper(II)-catalyzed trifluoromethylation of iodoarenes using Chen’s reagent,” Org. Chem. Front. 2018, 5, 1143-1147. Q. Lin, Y. Liu, Z. Xiao, L. Zheng, X. Zhou, Y. Guo, Q.-Y. Chen, C. Zheng,*C. Liu,*“Intermolecular oxidative radical fluoroalkylfluorosulfonylation of unactivated alkenes with (fluoroalkyl)trimethylsilane,silver fluoride, sulfur dioxide and N-fluorobenzenesulfonimide”,Org. Chem. Front. 2019, 6, 447-450. Y. Liu, Q. Lin, Z. Xiao, C. Zheng, Y. Guo, Q.-Y. Chen*, C. Liu*, Zinc-mediated Intermolecular reductive radical fluoroalkylsulfination of unsaturated carbon-carbon bonds with fluoroalkyl bromides and sulfur dioxide Chem. Eur. J. 2019, 25, 1824-1828 (Hot paper). Z. Su, Y. Guo*, Q.-Y. Chen*, Z.-G. Zhao,* B.-Y. Nian, Catalyst-free hydroxytrifluoromethylation of alkenes using iodotrifluoromethane, Chin. J. Chem. 2019, 37, 597-604. Q. Lin, Y. Liu, Z. Xiao, L. Zheng, X. Zhou, Y. Guo, Q.-Y. Chen, C. Zheng,*C. Liu,*“Intermolecular oxidative radical fluoroalkylfluorosulfonylation of unactivated alkenes with (fluoroalkyl)trimethylsilane,silver fluoride, sulfur dioxide and N-fluorobenzenesulfonimide”,Org. Chem. Front. 2019, 6, 447-450. Y. Liu, Q. Lin, Z. Xiao, C. Zheng, Y. Guo, Q.-Y. Chen*, C. Liu*, Zinc-mediated Intermolecular reductive radical fluoroalkylsulfination of unsaturated carbon-carbon bonds with fluoroalkyl bromides and sulfur dioxide Chem. Eur. J. 2019, 25, 1824-1828 (Hot paper). Z. Su, Y. Guo*, Q.-Y. Chen*, Z.-G. Zhao,* B.-Y. Nian, Catalyst-free hydroxytrifluoromethylation of alkenes using iodotrifluoromethane, Chin. J. Chem. 2019, 37, 597-604.