个人简历 1997.09-2001.07 厦门大学化学化工学院材料科学与工程系，学士 2001.09-2007.08 厦门大学化学化工学院化学系，博士 2007.08-2011.08 厦门大学化学化工学院化学系，助理教授 2012.04-2013.04 香港科技大学化学系，访问学者 2011.08-2018.08 厦门大学化学化工学院化学系，副教授 2018.08-至今 厦门大学化学化工学院，教授 荣誉与获奖 国家自然科学奖二等奖（2020，第二完成人） 福建省“雏鹰计划”青年拔尖人才 (2020) 福建省自然科学奖一等奖（2018，第二完成人） Thieme Chemistry Journals Award (2019) 福建省高等学校新世纪优秀人才 (2018) 福建省高校青年教师教学竞赛一等奖（2014）

经典有机反应的拓展，金属-碳多重键化学及导向有机合成的金属有机化学

Zhao, J.; Cai, Y.; Yang, X.; Zhang, H.* Heavier Group 14 Congeners of Metalla-isobenzenes: Access to Metalla-isosilabenzene and Metalla-isogermabenzene by One-Pot Reactions. Chin. J. Chem. 2024, 42, 1121-1127. Lin, Z.; Yan, Z.; Cai, Y.; Xuan, J.; He, N.; Zhang, H.* Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition. Organometallics. 2023. 42, 1615−1620 Lin, Z.;† Cai, Y.;† Zhang, Y.; Zhang, H.;* Xia, H.* Heterocyclic Suzuki–Miyaura coupling reaction of metalla-aromatics and mechanistic analysis of site selectivity. Chem. Sci. 2023,14, 1227-1233. Huang, F.; Yan, Z.; Zheng, X.; Cai, Y.; Zhang, H.;* Xia, H.* One-pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne. Chem. - Eur. J. 2022, 28, e202201229. Zhang, H.;* Thogersen, M. K.; Jamieson, C. S.; Xue, X.-S.; Jorgensen, K. A.;* Houk, K.* Ambimodal Transition States in Diels-Alder Cycloadditions of Tropolone and Tropolonate with N-Methylmaleimide. Angew. Chem. Int. Ed. 2021, 60, 24991-24996. Cai, Y.;† Hua, Y.;† Lu, Z.; Lan, Q.; Lin, Z.; Fei, J.; Chen, Z.; Zhang, H.;* Xia, H.* Electrophilic aromatic substitution reactions of compounds with Craig-Mobius aromaticity. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2102310118. Zhang, H.;* Novak, A. J. E.; Jamieson, C. S.; Xue, X. S.; Chen, S.; Trauner, D.;* Houk, K. N.* Computational Exploration of the Mechanism of Critical Steps in the Biomimetic Synthesis of Preuisolactone A, and Discovery of New Ambimodal (5 + 2)/(4 + 2) Cycloadditions. J. Am. Chem. Soc. 2021, 143, 6601-6608. Luo, M.;† Cai, Y.;† Lin, X.; Long, L.; Zhang, H.;* Xia, H.* Synthesis, Characterization and Reactivity of Metalla-chalcogenirenium Compounds. Chin. J. Chem. 2021, 39, 1558-1564. Zhang, J.-X.;† Sheong, F. K.;† Lu, Z.; Zhang, H.;* Lin, Z.* Unexpected Electronic Behavior of Organic Azide and Metal‐Carbyne in Their 1,3‐Dipolar Cycloaddition Reaction. Chin. J. Chem. 2020, 38, 1565-1570.(Zhang and Sheong contributed equally to this work.) Huang, F.; Zheng, X.; Lin, X.; Ding, L.; Zhuo, Q.; Wen, T. B.; Zhang, H.;* Xia, H.* Extension of the Simmons–Smith Reaction to Metal-carbynes: Efficient Synthesis of Metallacyclopropenes with σ-Aromaticity. Chem. Sci. 2020, 11, 10159-10166. Deng, Z.;† Wu, P.;† Cai, Y.; Sui, Y.; Chen, Z.; Zhang, H.; Wang, B.;* Xia, H.* Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations. iScience 2020, 23, 101379. (Deng and Wu contributed equally to this work.) Lin, J.; Xu, Q.; Lin, X.; Hua, Y.; Chen, D.; Ruan, Y.; Zhang, H.;* Xia, H.* The First OCCCO Pentadentate Chelates: Osmium Mediated Stepwise Oxidations of Terminal Alkynes by Pyridine N‐Oxide. Chin. J. Chem. 2020, 38, 1273-1279. Luo, M.; Hua, Y.; Zhuo, K.; Long, L.; Lin, X.; Deng, Z.; Lin, Z.; Zhang, H.; Chen, D.; Xia, H.* Carbolong Chemistry: Planar CCCCX-Type (X = N, O, S) Pentadentate Chelates by Formal [3+1] Cycloadditions of Metalla-Azirines with Terminal Alkynes. CCS Chemistry 2020, 2, 758-763. Luo, M.; Sui, Y.; Lin, X.; Zhu, C.; Yan, Z.; Ruan, Y.; Zhang, H.;* Xia, H.* [3+2] Cycloaddition Reaction of Metallacyclopropene with Nitrosonium Ion: Isolation of Aromatic Metallaisoxazole. Chem. Commun. 2020, 56, 6806 - 6809. Ni, D.; Witherspoon, B. P.; Zhang, H.; Zhou, C.; Houk, K. N.;* Brown, M. K.* Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes. Angew. Chem., Int. Ed. 2020, 59, 11432-11439. Lu, Z.;† Zhu, Q.;† Cai, Y.; Chen, Z.; Zhuo, K.; Zhu, J.; Zhang, H.;* Xia, H.* Access to Tetracyclic Aromatics with Bridgehead Metals via Metalla-click Reactions. Sci. Adv. 2020, 6, eaay2535. Zhuo, Q.;† Zhang, H.;† Ding, L.; Lin, J.; Zhou, X.; Hua, Y.; Zhu, J.; Xia, H.* Rhodapentalenes: Pincer Complexes with Internal Aromaticity. iScience 2019, 19, 1214-1224. Luo, M.; Deng, Z.; Ruan, Y.; Cai, Y.; Zhuo, K.; Zhang, H.;* Xia, H. Reactions of Metallacyclopentadiene with Terminal Alkynes: Isolation and Characterization of Metallafulvenallene Complexes. Organometallics 2019, 38, 3053-3059. Lin, J.; Ding, L.; Zhuo, Q.; Zhang, H.;* Xia, H.* Formal [2+2+2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex. Organometallics 2019, 25, 5077-5085. Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun. 2019, 10, 1488. Li, J.; Lin, Y. M.;* Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.* Access to Metal-Bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. - Eur. J. 2019, 25, 5077-5085. Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin. J. Chem. 2018, 36, 1156-1160. Zhuo, Q.;† Zhang, H.;† Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H.* Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring. Sci. Adv. 2018, 4 (6), eaat0336. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M.;* Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37, 1788-1794. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H. A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1,2-Α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne. Chem. Commun. 2018, 54, 4009-4012. Zhou, X.; Zhang, H.* Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 2018, 24, 8962-8973. Hua, Y.; Zhang, H.;* Xia, H.* Aromaticity: History and Development. Chin. J. Org. Chem. 2018, 38, 11-28.