彭谦 照片

彭谦

研究员 博导

所属大学: 南开大学

所属学院: 化学学院

邮箱:
qpeng@nankai.edu.cn

个人主页:
https://chem.nankai.edu.cn/2019/0906/c24386a564046/page.htm

个人简介

2000-2004 中山大学 本科 理学学士 2004-2009 中国科学院上海有机所 博士(师从吴云东院士) 理学博士 2009-2010 中国科学院上海有机所 助理研究员 2010-2013 美国University of Notre Dame 博士后 2013-2014 美国Texas A&M University 高级研究学者 2014-2016 英国Univeristy of Oxford 玛丽居里研究员 2017-至今 南开大学化学学院 特聘研究员

研究领域

理论有机化学,计算化学,分子波谱模拟

近期论文

Bin Lu, Xinyi Liang, Jinyu Zhang, Zijian Wang, Qian Peng,* and Xiaoming Wang*, Dirhodium(II)/ Xantphos Catalyzed Relay Carbene Insertion and Allylic Alkylation Process: Reaction Development and Mechanistic Insights. J. Am. Chem. Soc., 2021,11799-11810. Jie Dong#, Hong-De An#, Ze-Kun Yue#, Sheng-Li Hou, Yao Chen*, Zhen-Jie Zhang, Peng Cheng, Qian Peng*, Bin Zhao*,Dual-Selective Catalysis in Dephosphorylation Tuned by Hf6-Containing MetalOrganic Frameworks Mimicking Phosphatase, ACS Central Science, 2021, 7, 831-840. Huan Zhang#; Enhui Wang#; Shasha Geng; Zhengli Liu; Yun He; Qian Peng*; Zhang Feng*; Experimental and Computational Studies on the Iron‐Catalyzed Selective and Controllable Defluorosilylation of Unactivated Aliphatic gem-Difluoroalkenes, Angew. Chem. Int. Ed., 2021, 60, 10211-10218. Xia Zhong; Ziwei Zhong; Zhikun Wu; Zhen Ye; Yuxiang Feng; Shunxi Dong; Xiaohua Liu*; Qian Peng*; Xiaoming Feng*; Chiral Lewis acid-bonded picolinaldehyde enables enantiodivergent carbonyl catalysis in the Mannich/condensation reaction of glycine ester, Chemical Science, 2021, 12, 4353-4360. Cheng Xu, # Zhen Ye, # Li Xiang, Shuhan Yang, Qian Peng,* Xuebing Leng, Yaofeng Chen* Insertion of Metal-substituted Silylene into Naphthalene’s Aromatic Ring and Subsequent Rearrangement for Silaspiro-benzocycloheptenyl and Cyclobutenosilaindan Derivatives. Angew. Chem. Int. Ed. 2021, 60, 3189-3195. Jiawen Wang,# Sujuan Zheng,# Subramani Rajkumar, Jinglei Xie, Na Yu, Qian Peng,* Xiaoyu Yang* Chiral phosphoric acid catalyzed stereodivergent synthesis of trisubstituted allenes and computational mechanistic studies. Nature Communication 2020, 11,5527. Lei Kang,# Yongjia Lin,# Zeng Gao, Jinlong Zhang, Huameng Yang, Jinlong Qian,* Qian Peng,* Gaoxi Jiang*, Fluorine Effect for Tuning C-C and C-S Bond Cleavage in Fluoro-Julia-Kocienski Intermediates, CCS Chem, 2020, 2, 1678-1689. Tao Zhang, Yu-Xin Luan, Su-Juan Zheng, Qian Peng*, Mengchun Ye* Chiral Aluminum-Controlled Ni-catalyzed Enantioselective Synthesis of Indenes via C-CN Bond Activation. Angew. Chem. Int. Ed. 2020, 59, 7439 –7443. Bo Zhou, Ying-Qi Zhang, Kairui Zhang, Yang-Bo Chen, You Li, Qian Peng,* Shou-Fei Zhu,* Qi-Lin Zhou,and Long-Wu Ye*,Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement. Nature Communication 2019.10,3234. Guangzhu Wang#, Xinyi Liang#, Lili Chen, Qian Gao, Jian-Guo Wang, Panke Zhang,* Qian Peng,* and Senmiao Xu*, Iridium-Catalyzed Distal Hydroboration of Aliphatic Internal Alkenes. Angew. Chem. Int. Ed. 2019, 58, 8187-8191. Jianping Zhao#, Qian Peng#,Zijian Wang, Wei Xu, Hongyan Xiao, Qi Wu, Hao-Ling Sun, Fang Ma,Jiyong Zhao, Cheng-Jun Sun, Jianzhang Zhao, and Jianfeng Li*, Proton mediated spin state transition of cobalt heme analogues, Nature Communication 2019. 10, 2303. Xian-Shuang Tu, Ning-Ning Zeng, Ru-Ye Li, Yu-Quan Zhao, De-Zhen Xie, Qian Peng* and Xiao-Chen Wang*. C2-Symmetric Bicyclic Bis-Borane Catalysts: Kinetic or Thermodynamic Products from a Reversible Hydroboration of Dienes. Angew. Chem. Int. Ed. 2018, 57, 15096-15100. Fengmin Guo, Zekun Yue, Marko Trajkovski, Xiaoping Zhou, Dong Cao, Qiang Li, Baifan Wang, Xin Wen, Janez Plavec*, Qian Peng*, Zhen Xi, and Chuanzheng Zhou*.Effect of Ribose Conformation on RNA Cleavage via Internal Transesterification. J. Am. Chem. Soc. 2018, 140, 11893-11897. Subramani Rajkumar#, Jiawen Wang#, Sujuan Zheng, Donglei Wang, Xueqian Ye, Xuejiao Li, Qian Peng*, Xiaoyu Yang*, Regioselective and enantioselective synthesis of β-indolyl cyclopentenamides through chiral anion catalysis. Angew. Chem. Int. Ed. 2018, 57,13489 –13494. Hao Wang, Zibo Bai, Tangqian Jiao, Zhiqiang Deng, Huarong Tong, Gang He*, Qian Peng*, and Gong Chen*.Palladium-Catalyzed Amide-Directed Enantioselective Hydrocarbo-functionalization of Unactivated Alkenes Using a Chiral Monodentate Oxazoline Ligand. J. Am. Chem. Soc. 2018, 140, 3542-3546. Qian Peng*, Zengwei Wang, Snezana D. Zaric, Edward N. Brothers, and Michael B. Hall*.Unraveling the Role of a Flexible Tetradentate Ligand in the Aerobic Oxidative Carbon-Carbon Bond Formation with Palladium Complexes: A Computational Mechanistic Study. J. Am. Chem. Soc. 2018, 140, 3929-3939. Meng-Yang Hu, Qiao He, Song-Jie Fan, Zi-Chen Wang, Luo-Yan Liu, Yi-Jiang Mu, Qian Peng* and Shou-Fei Zhu*,Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation. Nature Communication 2018. 9, 221. Arghya Deb, Avijit Hazra, Qian Peng*, Robert S. Paton*, Debabrata Maiti*, Detailed Mechanistic Studies on Palladium Catalyzed Stereoselective C–H Olefination with Aliphatic Alkenes: A Significant Influence of Proton Shuttling. J. Am. Chem. Soc. 2017, 136, 763-775. Robert Strack, Qian Peng*, Aroonroj Mekareeya‎, Robert.Paton* and Edward Anderson*, Computational Ligand Design in Enantio- and Diastereoselective Ynamide [5+2] Cycloisomerization, Nature Communication 2016. 7:10109.