中国科学院院士，南开大学教授。2002年获国家自然科学基金委杰出青年基金资助，2004年被评为“教育部领军人才项目”特聘教授。2017年评为首批天津市杰出人才。2021年当选中国科学院院士。长期从事功能配合物化学研究，在配位聚合物的功能导向构筑、结构调控及性能研究等方面取得了系统成果，在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Adv. Mater.、Nat. Commun.等期刊发表学术论文600余篇；主编《配位聚合物化学》专著一部，副主编《配位化学》教材一部，参编其他专著与教材6部。以第一完成人获2014年度国家自然科学二等奖、2018年度天津市自然科学特等奖、2002及2011年度天津市自然科学一等奖等奖项。

光学材料 磁性材料 能源材料 气体吸附与分离研究 功能配位化学

Self-Recoverable Elastico Mechanoluminescence Of a Hybrid Metal Halide Crystal Yang, T.-Y., Li, S.-N., Chen, H.-S., Li, Z.-Y., Li, Z.-G., Feng, R., Gao, F.-F., Zhang, Y., Liu, Y.-M., Zhang, Y., Liu, W.-W., Li, W.*, Bu, X.-H., Natl. Sci. Rev. 2024, nwae372. Precisely Tuning Band Gaps of Hexabenzocoronene-Based MOFs Toward Enhanced Photocatalysis Zhang, H.,Li, C.,Lang, F.,Li, M.,Liu, H.,Zhong, D.-C.,Qin, J.-S.,Di, Z.,Wang, D.-H.,Zeng, L.,Pang, J.*,Bu, X.-H.*, Angew. Chem. Int. Ed.2024, e202418017. Strategic Defect Engineering Enabled Efficient Oxygen Evolution Reaction in Reconstructed Metal‐Organic Frameworks Zhang, Y.-Q., Liu, M., Zhang, L.-T., Lu, N., Wang, X., Li, Z.-G., Zhang, X.-H., Li, N.*, Bu, X.-H.*,Adv. Funct. Mater. 2024, 2412406. Efficient Fluorocarbons Capture Using Radical-Containing Covalent Triazine Frameworks Zhang, Z., Zhang, S., Liu, X., Li, L., Wang, S., Yang, R., Zhang, L., You, Z., Shui, F., Yang, S., Yang, Z., Zhao, Q., Li, B.*, Bu, X.-H., J. Am. Chem. Soc. 2024, 146, 31213-31220. Bioinspired “Intermolecular Pocket” in Soft Molecular Crystal of Porous Organic Cage Exhibiting Reversible Guest Recognition Zhang, L.,Lei, Q.,Yi, M.,Zhang, Z.,Lian, X.,Xu, J.,Zhang, S.*,Li, L.*,Li, B.*,Bu, X.-H., Angew. Chem. Int. Ed.2024, e202421753. Optimizing Hygroscopic Metal–Organic Frameworks via EDTA‐Mediated Structural Reinforcement and Photothermal Modification Cheng, M.,Lian, X.,Bai, H.,Wang, X.,Xu, J.,Cao, M.*,Bu, X.-H.*, Adv. Funct. Mater.2024,2416241. Xenon Regeneration by CO2 Removal from Exhaled Anesthetic Gas Mixture by a Hybrid Ultramicroporous Material with Customized Nanotrap Nie, H.-X.,Yu, M.-H.,Huang, H.,Liu, S.-S.,Jia, J.-Z.,Li, L.,Chang, Z.*,Zaworotko, M. J.,Bu, X.-H.*, Adv. Funct. Mater.2024, 2414933. Solution‐Processable Metal‐Organic Framework Featuring Highly Tunable Dynamic Aggregation States Geng, L., Qiao, Y., Sun, R., Guo, L., Li, Z.-Q., Ma, Y., Yu, M.-H.*, Chang, Z.*, Bu, X.-H.*, Adv. Mater. 2024, 2415511. A Hydrolytically Stable Metal–Organic Framework for Simultaneous Desulfurization and Dehydration of Wet Flue Gas Pang, J.-J., Yao, Z.-Q., Huang, H.-L., Li, L., Li, Q.-W., Lu, N., Song, Z.-H., Xu, J.*, Bu, X.-H., Angew. Chem. Int. Ed. 2024, e202421681. Supramolecular Assembly Enhanced Linear and Nonlinear Chiroptical Properties of Chiral Manganese Halides Han, X., Cheng, P., Yang, H., Guan, J., Xin, M., Li, G., Li, X., Zheng, Y.*, Xu, J.*, Bu, X.-H., Angew. Chem. Int. Ed. 2024, e202419776. Stimulus-Induced Dynamic Behavior Regulation of Flexible Crystals through the Tuning of Module Rigidity Fang,H., Liu,X.-Y., Ding,H.-J., Mulcair,M.,Space,B., Huang,H.,Li,X.-W., Zhang,S.-M., Yu,M.-H*, Chang,Z.*, and Bu, X.-H.*,J. Am. Chem. Soc. 2024, 146, 14357−14367. Unusual Pressure-Induced Self-Trapped Exciton to Free Exciton Transfer in Chiral 2D Lead Bromide Perovskites Gao, F. F., Qin, Y., Li, Z. G., Li, W.*, Hao, J., Li, X., Liu, Y. G., Howard, CJ., Wu, X., Jiang, X. X., Lin, Z. S., Lu, P. X., Bu, X.-H.*, ACS Nano. 2024, 18, 4, 3251–3259. Liquid-Phase Exfoliation of 3D Metal-Organic Frameworks into Nanosheets Ji, L. J., Yang, T. Y., Feng, G. Q., Li, S., Li, W.*, Bu, X.-H., Adv. Mater. 2024, 36, 2404756. Chirality-Mediated 1D-to-2D Phase Transition in Hybrid Lead Halide Perovskites Li, Z. G., Dong, X. H., Song, H. P., Huang, S. S., Hu, H., Zhang, Y., Wu, X., Li W.*, Bu X.-H., J. Am. Chem. Soc. 2024, 146, 40, 27946-27955. Precisely Tuning Band Gaps of Hexabenzocoronene-Based MOFs Toward Enhanced Photocatalysis Zhang, H., Li, C., Lang, F. F., Li, M., Liu, H. Y., Zhong, D. C., Qin, J. S., Di, Z. Y., Wang, D. H., Zeng, L., Bu, X.-H., Pang, J. D.*, Angew. Chem. Int. Ed. 2024, e202418017. Giant Emission Enhancement from Hybrid Manganese Bromide Via Pressure-Induced Band-Edge Carrier Reconfiguration Li, Z. G., Li, K., Gao, F. F., Chen, Y. Q., Li, W.*, Bu, X.-H.*, Adv. Funct. Mater. 2024, 34, 2313683. Leveraging Surface Chemistry and Pore Shape Engineering in a Metal-Organic Framework for One-Step Olefin Purification Lian, X., Liu, P. X., Yuan, Y. C., Pang, J. J., Li, L., Liu, S. S., Yue, B., Zhang, Y. H., Li, L. B., Xu, J.*, Bu, X.-H., Adv. Funct. Mater. 2024, 34, 2312150. A High Working Temperature Multiferroic Induced by Inverse Temperature Symmetry Breaking Zhan, L. Y., Zhou, Y., Li, N., Zhang, L. J., Xi, X. J., Yao, Z. Q., Zhao, J. P.*, Bu, X.-H.*, J. Am. Chem. Soc. 2024, 146, 8, 5414–5422. Ferredoxin-Inspired Design of S-Synergized Fe-Fe Dual-Metal Center Catalysts for Enhanced Electrocatalytic Oxygen Reduction Reaction Liu, M., Wang, X. M., Cao, S. F., Lu, X. Q., Li, W., Li, N.*, Bu, X.-H.*, Adv. Mater. 2024, 36, 2309231. Two-Dimensional Spin-Crossover Molecular Solid Solutions with Tunable Transition Temperatures across 90 K Wu, Y. Y., Li, Z. Y.*, Peng, S., Zhang, Z. Y., Cheng, H. M., Su, H., Hou, W. Q., Yang, F. L.*, Wu, S. Q., Sato, O., Dai, J. W., Li, W.*, Bu X.-H.*, J. Am. Chem. Soc. 2024, 146, 12, 8206–8215. Boosted Second Harmonic Generation of a Chiral Hybrid Lead Halide Resonant to Charge Transfer Exciton from Metal Halide Octahedra to Ligand Cheng, P. X., Jia, X. D., Chai, S. Q., Li, G., Xin, M. Y., Guan, J. J., Han, X., Han, W. Q., Zeng, S. M., Zheng, Y. S., Xu, J. L.*, Bu, X.-H. Angew. Chem. Int. Ed. 2024, 63, e202400644. Reticular Modulation of Piezofluorochromic Behaviors in Organic Molecular Cages by Replacing Non-Luminous Components Li, Y., Wang, K., Feng, R., Wang, J. T., Xi, X. J., Lang, F. F., Li, Q. W., Li, W., Zou, B., Pang, J. D.*, Bu, X.-H.*, Angew. Chem. Int. Ed. 2024, 63, e202403646. Triazacoronene-Based 2D Conductive Metal-Organic Framework for High-Capacity Lithium Storage Yin, J. C., Lian, X., Li, Z. G., Cheng, M. R., Liu, M., Xu, J., Li, W., Xu, Y. H., Li, N.*, Bu, X.-H.*, Adv. Funct. Mater. 2024, 34, 2403656. Utilizing Shear Piezoelectricity of Chiral Lead-Free Metal Halides for Electromechanical Sensing Gong, Y. J., An, L. C., Zhang, Y., Zhao, C., Li, Z. G., Guo, T. M., He, M., Yu, J., Li, W.*, Bu, X.-H., Adv. Funct. Mater. 2024, 34, 2402649. Low-power, non-coherent light-triggered two-photon absorption via extending the lifetime of the transition state Zeng, L., Wang, X. Y., Li, N., Pang, J. D., Bu, X.-H.*, Coord. Chem. Rev. 2024, 511, 215868. Metalation of metal-organic frameworks: fundamentals and applications Li, H. Y., Kong, X. J., Han, S. D., Pang, J. D.*, He, T.*, Wang, G. M.*, Bu, X.-H., Chem. Soc. Rev. 2024, 53, 5626-5676. Planar Chlorination Engineering: A Strategy of Completely Breaking the Geometric Symmetry of Fe-N4 Site for Boosting Oxygen Electroreduction Wei, S. J., Yang, R. Y., Wang, Z. Y., Zhang, J. J.*, Bu, X.-H.*, Adv. Mater. 2024, 36, 2404692. Programming Piezoelectric Phase of Poly(Vinylidene Fluoride) via Hybrid Metal Halide Perovskite for Enhanced Electromechanical Performance Gong, Y. J., Li, Z. G., Guo, T. M., Zhao, C., Zhang, Y., He, M., Yu, J., Li, W.*, Bu, X.-H., Adv. Energy Mater. 2024, 14, 2400241. Surface-Grafted Single-Atomic Pt-Nx Complex with a Precisely Regulating Coordination Sphere for Efficient Electron Acceptor-Inducing Interfacial Electron Transfer Zhang, X. H., Li, Z. G., Li, H. X., Yang, D., Ren, Z. H., Zhang, Y. Q., Zhang, J. J.*, Bu, X.-H.*, Angew. Chem. Int. Ed. 2024, 63, e202404386. Supramolecular Assembly Frameworks (SAFs): Shaping the Future of Functional Materials Tang, X. H., Pang, J. D., Dong, J. Q.*, Liu, Y.*, Bu, X.-H.*, Cui, Y.*, Angew. Chem. Int. Ed. 2024, 63, e202406956. Harnessing triplet excitons: Advances in luminescence metal coordination compounds Geng, L., Sun, R., Zhang, D. S., Yu, M. H.*, Chang, Z.*, Bu, X.-H.*, Coord. Chem. Rev. 2024, 518, 216066. Macroscopic Twisting of Chiral Metal Halide Single Crystals Driven by Thermo-Induced Topochemical Dehydration Xin, M. Y., Cheng, P. X., Shi, R. C., Guan, J. J., Han, X., Wang, Z. H., Li, Q. W., Li, G., Zheng, Y. S., Xu, J. L.*, Bu, X.-H., J. Am. Chem. Soc. 2024, 146, 38, 26534–26542. Porous Organic Cage as an Efficient Platform for Industrial Radioactive Iodine Capture Liu, X. L., Zhang, Z. Y., Shui, F., Zhang, S., Li, L., Wang, J. H., Yi, M., You, Z. F., Yang, S. Q., Yang, R. F., Wang, S., Liu, Y. L., Zhao, Q., Li, B. Y.*, Bu, X.-H.*, Ma, S. Q.*, Angew. Chem. Int. Ed. 2024, 63, e202411342. Engineering Hygroscopic MOF-Based Silk Via Bioinspired Interfacial Assembly for Fast Moisture Manipulation Cheng, M. R., Bai, H. Y., Wang, X. S., Chang, Z., Cao, M. Y.*, Bu, X.-H.*, Adv. Mater. 2024, 2411680. Facile Tuned TSCT-TADF in Donor-Acceptor MOF for Highly Adjustable Photonic Modules Based on Heterostructures Crystals Zhang, B., Xu, J., Li, C. T., Huang, H. L., Chen, M. X., Yu, M. H., Chang, Z.*, Bu, X.-H., Angew. Chem. Int. Ed. 2023, 135, e202303262. General Approach to Construct C−C Single Bond-Linked Covalent Organic Frameworks Feng, X. N., Yang, Y., Cao, X. J., Wang, T., Kong, D. M., Yin, X. B.*, Li, B. Y.*, Bu, X.-H., J. Am. Chem. Soc. 2023, 145, 21284-21292. Free Halogen Substitution of Chiral Hybrid Metal Halides for Activating the Linear and Nonlinear Chiroptical Properties Guan, J. J., Zheng, Y. S., Cheng, P. X., Han, W. Q., Han, X., Wang, P. H., Xin, M. Y., Shi, R. C., Xu, J. L.*, Bu, X.-H., J. Am. Chem. Soc. 2023, 145, 26833-26842. Synergistic Effect of Organic Ligands on Metal Site Spin States in 2D Metal−Organic Frameworks for Enhanced ORR Performance Wei, X. F., Jiang, C. H., Xu, H. K., Ouyang, Y. G., Wang, Z. F., Lu, C. Y., Lu, X. Q., Pang, J. D.*, Dai, F. N.*, Bu, X.-H., ACS Catal. 2023, 13, 15663-15672. Reticular Synthesis of Highly Crystalline Three-Dimensional Mesoporous Covalent-Organic Frameworks for Lipase Inclusion Liu, H. Y., Zhou, Y., Guo, J. B., Feng, R., Hu, G. L., Pang, J. D.*, Chen, Y.*, Terasaki, O., Bu, X.-H., J. Am. Chem. Soc. 2023, 145, 23227-23237. Chiral Two-Dimensional Hybrid Organic-Inorganic Perovskites for Piezoelectric Ultrasound Detection Guo, T. M., Gao, F. F., Gong, Y. J., Li, Z. G., Wei, F. X., Li, W.*, Bu, X.,-H., J. Am. Chem. Soc. 2023, 145, 22475-22482. Immobilization of the Polar Group into an Ultramicroporous Metal−Organic Framework Enabling Benchmark Inverse Selective CO2/C2H2 Separation with Record C2H2 Production Yang, S. Q., Krishna, R., Chen, H. W., Li, L. B., Zhou, L., An, Y. F., Zhang, F. Y., Zhang, Q., Zhang, Y. H., Li, W., Hu, T. L.*, Bu, X.-H., J. Am. Chem. Soc. 2023, 145, 13901-13911. Photosystem II Inspired NiFe-Based Electrocatalysts for Efficient Water Oxidation via Second Coordination Sphere Effect Liu, M., Li, N.*, Wang, X. M., Zhao, J., Zhong, D. C., Li, W., Bu, X.-H.*, Angew. Chem. Int. Ed. 2023, 62, e202300507. Pressure-Tuned Multicolor Emission of 2D Lead Halide Perovskites with Ultrahigh Color Purity Gao, F. F., Song, H. P., Li, Z. G., Qin, Y.*, Li, X., Yao, Z. Q., Fan, J. H., Wu, X., Li, W.*, Bu, X.-H.*, Angew. Chem. Int. Ed. 2023, 62, e202218675. Stabilizing Redox-Active Hexaazatriphenylene in a 2D Conductive Metal-Organic Framework for Improved Lithium Storage Performance Yin, J. C., Li, N.*, Liu, M., Li, Z. G., Wang, X. M., Cheng, M. R., Zhong, M., Li W., Xu, Y. H., Bu, X.-H.*, Adv. Funct. Mater. 2023, 33, 2211950. High Power Density Energy Harvesting and Human Motion Monitoring with [Trimethylchloromethylammonium][CdCl3]/Polymer Composite Gong, Y. J., Li, Z. G., Chen, H. S., Guo, T. M., Gao, F. F., Chen, G. J., Zhang, Y., You, Y. M., Li, W.*, He, M., Bu, X.-H., Yu, J.*, Matter 2023, 6, 2066–2080. Chemically stable guanidinium covalent organic framework for the efficient capture of low-concentration iodine at high temperatures Zhang, Z., Dong, X., Yin, J., Li, Z.-G., Li, X., Zhang, D., Pan, T., Lei, Q., Liu, X., Xie, Y., Shui, F., Li, J., Yi, M., Yuan, J., You, Z., Zhang, L., Chang, J., Zhang, H., Li, W., Fang, Q., Li, B.*, Bu, X.-H.*, Han, Y.*, J. Am. Chem. Soc. 2022,144(15), 6821-6829. Dangling octahedra enable edge states in 2D lead halide perovskites Qin, Y., Li, Z.-G., Gao, F.-F., Chen, H., Li, X., Xu, B., Li, Q., Jiang, X., Li, W.*, Wu, X., Quan, Z., Ye, L., Zhang, Y.*, Lin, Z., Pedesseau, L., Even, J.*, Lu, P., Bu, X.-H.*, Adv. Mater. 2022,34(29), 2201666. Plastic bending in a semiconducting coordination polymer crystal enabled by delamination An, L.-C., Li, X., Li, Z.-G., Li, Q., Beldon, P. J., Gao, F.-F., Li, Z.-Y., Zhu, S., Di, L., Zhao, S., Zhu, J., Comboni, D., Kupenko, I., Li, W.*, Ramamurty, U.*, Bu, X.-H.*, Nat. Commun. 2022,13(1), 6645. Dynamic full-color tuning of organic chromophore in a multi-stimuli-responsive 2D flexible MOF Yao, Z.-Q., Wang, K., Liu, R., Yuan, Y.-J., Pang, J.-J., Li, Q. W., Shao, T. Y., Li, Z. G., Feng, R., Zou, B., Li, W., Xu, J.*, Bu, X.-H.*, Angew. Chem., Int. Ed. 2022,61(17), e202202073. Multifunctional chiral 2D lead halide perovskites with circularly polarized photoluminescence and piezoelectric energy harvesting properties Qin, Y., Gao, F.-F., Qian, S., Guo, T.-M., Gong, Y.-J., Li, Z.-G., Su, G.-D., Gao, Y., Li, W.*, Jiang, C.*, Lu, P., Bu, X.-H.*, ACS Nano 2022,16(2), 3221-3230. Origin of ferroelectricity in two prototypical hybrid organic–inorganic perovskites Li, K., Li, Z.-G., Xu, J., Qin, Y., Li, W.*, Stroppa, A., Butler, K. T.*, Howard, C. J., Dove, M. T., Cheetham, A. K., Bu, X.-H.*, J. Am. Chem. Soc. 2022,144(2), 816-823. Installation of synergistic binding sites onto porous organic polymers for efficient removal of perfluorooctanoic acid Liu, X., Zhu, C., Yin, J., Li, J., Zhang, Z., Li, J., Shui, F., You, Z., Shi, Z., Li, B.*, Bu, X.-H.*, Nafady, A., Ma, S.*, Nat. Commun. 2022,13(1), 2132. Real-time in situ volatile organic compound sensing by a dual-emissive polynuclear Ln-MOF with pronounced Ln luminescence response Pang, J.-J., Yao, Z.-Q.*, Zhang, K., Li, Q.-W., Fu, Z.-X., Zheng, R., Li, W., Xu, J.*, Bu, X.-H., Angew. Chem., Int. Ed. 2023,62(7), e202217456. Elastic properties related energy conversions of coordination polymers and metal–organic frameworks Li, K., Qin, Y., Li, Z.-G., Guo, T.-M., An, L.-C., Li, W.*, Li, N.*, Bu, X.-H.*, Coord. Chem. Rev. 2022,470, 214692. Recent progress in host–guest metal–organic frameworks: construction and emergent properties Liu, X. T., Qian, B. B., Zhang, D. S., Yu, M. H.*, Chang, Z.*, Bu, X. H., Coord. Chem. Rev. 2023,476, 214921 Chiral hybrid copper(I) halides for high efficiency second harmonic generation with a broadband transparency window Ge, F., Li, B.-H., Cheng, P., Li, G., Ren, Z., Xu, J.*, Bu, X.-H., Angew. Chem., Int. Ed. 2022,61(10), e202115024. Energy level engineering: Ru single atom anchored on Mo-MOF with a [Mo8O26(im)2]4– structure acts as a biomimetic photocatalyst Wang, S., Zhang, J.-J., Zong, M.-Y., Xu, J., Wang, D.-H.*, Bu, X.-H., ACS Catal. 2022,12(13), 7960-7974. Induction of chiral hybrid metal halides from achiral building blocks Zheng, Y., Han, X., Cheng, P., Jia, X., Xu, J.*, Bu, X.-H., J. Am. Chem. Soc. 2022,144(36), 16471-16479. Electrochemically active sites inside crystalline porous materials for energy storage and conversion Kong, L. J., Zhong, M.*, Shuang, W., Xu, Y.*, Bu, X. H.* Chem. Soc. Rev. 2020, 49, 8, 2378 Metal–Organic Framework Materials for the Separation and Purification of Light Hydrocarbons Cui, W. G., Hu, T. L.*, Bu, X. H.* Adv. Mater. 2020, 32, 3, 1806445 Halide Perovskites for Nonlinear Optics Xu, J.*, Li, X., Xiong, J., Yuan, C., Semin, S., Rasing, T., Bu, X. H.* Adv. Mater. 2020, 32, 3, 1806736​ Metal–Organic-Framework-Based Photocatalysts Optimized by Spatially Separated Cocatalysts for Overall Water Splitting Zhang, J., Bai, T., Huang, H., Yu, M. H., Fan, X., Chang, Z., Bu, X. H.* Adv. Mater. 2020, 32, 49, 2004747