教育和工作经历 2021.01-至今 PI，北京大学化学学院无机所工作，博雅特聘教授 2018.01-2020.12，北京大学化学学院有机所工作，博雅特聘教授 2016.08-2017.12，北京大学化学学院有机所工作，教授 2009.10-2009.12，日本理化学研究所客座研究员 2007.10-2016.07，北京大学化学学院有机所工作，副教授 2004.11-2007.09，日本理化学研究所博士后 2004.01-2004.03，日本北海道大学JST研究员 2002.10-2004.10，北京大学化学学院博士后 1999.09-2002.09，南开大学化学学院，理学博士 1996.09-1999.06，广西师范大学化学与药学学院，理学硕士 1992.09-1996.07，湖南师范大学化学化工学院，化学教育学士 部分荣誉及奖励 2024年获国家自然科学奖二等奖（2/5) 2024年获首届“武创源”国际光化学及绿色制造技术创新大赛创新引领奖 2019年获宝钢优秀教师奖 2019年获北京大学优秀博士学位论文指导教师 2017年获国家杰出青年科学基金 2016年获杨芙清王阳元院士优秀教学科研奖 2015年获Thieme Chemistry Journals Award

金属有机化学，元素有机化学，计算化学，金属/元素有机化学驱动的机器学习，配位化学和晶体学。

Congyu Gao, Ting Ren, Yuanyuan Liu, Xiangkun Meng, Junpeng Liu, Zeli Song, Jianfeng Hu, Yong Yang*, Wen-Xiong Zhang*, and Hao Zhang*, Enantioselective Construction of Planar, Axially and Central Chiral Ferrocenyl Phosphines via a Pd-Catalyzed Domino Reaction and Diastereoselective Phosphination, Org. Chem. Front. 2024, 11, 5908–5913. Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, and Wen-Xiong Zhang*, Cascade C−H Activation and Two C−C Bond Forming in Reaction of Azalutetacyclopentadiene with 2-Methylbenzonitriles, Chem. Eur. J. 2024, 30, e20240231. Dajiang Huang#, Wei Liu#, Yu Zheng, Rui Feng, Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Nonplanar Aromaticity of Dinuclear Rare-Earth Metallacycles, J. Am. Chem. Soc. 2024, 146, 15609–15618. ( #Authors contributed equally) Peifeng Mei, Zibin Ma, Yu Chen, Yue Wu, Wei Hao, Qinghua Fan, and Wen-Xiong Zhang*, Chiral Bisphosphine Ph-BPE Ligand: A Rising Star in Asymmetric Synthesis, Chem. Soc. Rev. 2024, 53, 6735-6778. Zhiqiang Hao, Zhongzhen Wang, Dajiang Huang, Xinlei Huangfu, Xuejing Yang, Junnian Wei, Wei Liu*, and Wen-Xiong Zhang*, Harnessing Redox-Inactive Rare-Earth Metals for Photocatalytic Reductive Coupling of Benzyl Bromides, Green Synth. Catal. 2024, 5, XXXXX–XXXXX. Xinlei Huangfu#, Zhongzhen Wang#, Yu Chen#, Junnian Wei, Wei Liu*, and Wen-Xiong Zhang*, Recent Progress on the Functionalization of White Phosphorus in China, Natl. Sci. Rev. 2024, 11, nwae162. ( #Authors contributed equally) Wufeng Chen#, Ni Zhang#, Zhengqi Chai, Junnian Wei, Gen Luo* and Wen-Xiong Zhang*, Rare-Earth-Catalyzed Regiodivergent Hydrosilylation of Aryl Alkenes, ACS Catal. 2024, 14, 5612-5620. ( #Authors contributed equally) Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, and Wen-Xiong Zhang*, sp2-sp Cross-Carbanion Coupling at a Rare-Earth Center Leading to the Formation of Carbon-Carbon Double Bonds, Inorg. Chem. Front. 2024, 11, 2312-2318. Feifei Cao#, Congyu Gao#, Jingxin Zi, Jianfeng Hu, Yong Yang*, Wen-Xiong Zhang*, and Hao Zhang*, Palladium-Catalyzed Intramolecular C–H Arylation of Ferrocenyl-Sulfides, Sulfoxide and Its Application in Metal Ion Recognition, Green Synth. Catal. 2024, 5, XXXXX–XXXXX. Yu Chen, Wei Liu, Xinlei Huangfu, Junnian Wei, Jiangxi Yu*, and Wen-Xiong Zhang*, Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis, Chem. Eur. J. 2023, 29, e202302289. Wei Liu, and Wen-Xiong Zhang*, Colorless Zinc Colored by Metal-Metal Orbital Interaction, Chem 2023, 9, 3027–3029. (Preview) Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Rare-Earth Metallacycloheptatrienes: Synthesis, Structure and Reactivity, Organometallics 2023, 42, 2736–2741. Miaomiao Zhu#, Zhengqi Chai#, Tianyu Li, Junnian Wei, Ze-Jie Lv*, and Wen-Xiong Zhang*, Selective C−C Coupling of Two Nitriles Affording Rare-Earth Diazametallacyclopentadienes: Synthesis, Cooperative Reactivity and Mechanistic Studies, Inorg. Chem. Front. 2023, 10, 4569–4577. ( #Authors contributed equally) Wei Liu #, Yaqi Zhao #, Wangyang Ma, Zhengqi Chai, Yibo Liang, Ze-Jie Lv, Ling Xu, Junnian Wei, and Wen-Xiong Zhang*, Cross-Carbanion Coupling at a Rare-Earth Center, Cell Rep. Phys. Sci. 2023, 4, 101479. ( #Authors contributed equally) Xinlei Huangfu, Wei Liu, Hanhua Xu, Zhongzhen Wang, Junnian Wei, and Wen-Xiong Zhang*, Photochemical Benzylation of White phosphorus, Inorg. Chem. 2023, 62, 12009–12017. Haihan Yan, Botao Wu, Junnian Wei, and Wen-Xiong Zhang*, Insight into the Ligand-to-Ligand Charge-Transfer Process in Rare-Earth Metal Diradical Complexes, Inorg. Chem. 2023, 62, 8052–8057. Miaomiao Zhu#, Zhengqi Chai#, Ze-Jie Lv#, Tianyu Li, Wei Liu , Junnian Wei, and Wen-Xiong Zhang*, Selective Cleavage of the Strong or Weak C–C Bonds in Biphenylene Enabled by Rare-Earth Metals, J. Am. Chem. Soc. 2023, 145, 6633–6638 ( #Authors contributed equally) Ze-Jie Lv, Wei Liu, and Wen-Xiong Zhang*, Progress of Azametallacyclopentadienes in the New Century, Chem. Eur. J. 2023, 29, e202204079. (Invited Concept) Yaqi Zhao, Zhengqi Chai, Qingrui Zeng, and Wen-Xiong Zhang*, Overview of 1,5-Selective Click Reaction of Azides with Alkynes or Their Synthetic Equivalents, Molecules 2023, 28, 1400. (Invited Review) Jingyuan Hu, Zhengqi Chai, Wei Liu, Junnian Wei, Ze-Jie Lv and Wen-Xiong Zhang*, Direct and Chlorine-Free Synthesis of Phosphafluorenes or Their Oxides from White Phosphorus, Green Synth. Catal. 2023, 4, 330–333. Miaomiao Zhu, Tianyu Li, Zhengqi Chai, Junnian Wei, Ze-Jie Lv*, and Wen-Xiong Zhang*, Diversified Two-Electron Reduction for Trivalent Scandium Complexes with Arene Ligands, Inorg. Chem. Front. 2023, 10, 630–637. Zhiqiang Huang, Wei Liu, and Wen-Xiong Zhang*, Overview of 6π 1,5-Electrocyclization over the Past 40 Years, Chin. J. Chem. 2023, 40, 725–740. Zhengqi Chai, and Wen-Xiong Zhang*, Dicarbanion Compounds: The Bridge between Organometallic Reagents and Mononuclear Heterocycles, Organometallics 2022, 41, 3455–3477. (Review) Yu Zheng#, Chao Yu #, Botao Wu, Junnian Wei, and Wen-Xiong Zhang*, Synthesis, Structure, and Bonding of Spiro Rare-earth Metallacyclopent-3-enes via the Reduction of Metallacyclopentadienes, Cell Rep. Phys. Sci. 2022, 3, 100831. (#Authors contributed equally.) Haihan Yan, and Wen-Xiong Zhang*, Radical Rare-Earth Metal Complexes: Advances, Challenges and Prospects, J. Guangxi Norm. Univ. (Natural Science Edition) 2022, 40, 168–182. (Invited Review) Jingyuan Hu, Wei Liu, and Wen-Xiong Zhang*, Direct Functionalization of White Phosphorus by Organolithium Reagents to Organophosphorus Compounds, Phosphorus Sulfur Silicon Relat. Elem. 2022, 197, 398–407. (Invited Review) Jingyuan Hu, Zhengqi Chai, Wei Liu, Zhe Huang, Junnian Wei, and Wen-Xiong Zhang*, Phosphafluorenyl Lithiums: Direct Synthesis from White Phosphorus, Structure and Diversified Synthons, Sci. China Chem. 2022, 65, 322–327. Ze-Jie Lv, Miaomiao Zhu, Wei Liu, Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Reactivity of Lutetacyclopropene toward Benzyl, Benzoyl, and Trimethylsilyl Nitriles Affording Diversified Lutetium Complexes, Organometallics 2021, 40, 3992–3998. Ze-Jie Lv, Wei Liu, Miaomiao Zhu, Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Insertion Chemistry of Lutetacyclopropene toward Unsaturated C−O/C−N Bonds, Chem. Eur. J. 2021, 27, 16498–16504. Haihan Yan, Junnian Wei, and Wen-Xiong Zhang*, Synthesis, Structures and Reactivity of Diazabutadiene Ligated Rare-Earth Radical Complexes Bearing Adaptable Auxiliary Ligands, Organometallics 2021, 40, 3245–3252. (Cover Paper) Ze-Jie Lv, Zhengqi Chai, Miaomiao Zhu, Junnian Wei, and Wen-Xiong Zhang*, Selective Coupling of Lanthanide Metallacyclopropenes and Nitriles via Azametallacyclopentadiene and η2-Pyrimidine Metallacycle, J. Am. Chem. Soc. 2021, 143, 9151–9161. (Cover Paper) Jun Liu, Yong Yang, Kunbing Ouyang*, and Wen-Xiong Zhang*, Transition-Metal-Catalyzed Transformations of C-N Single Bonds: Advances in the Last Five Years, Challenges and Prospects, Green Synth. Catal. 2021, 2, 87–122. (Cover Paper) Yongliang Zhang, Chao Yu, Zhe Huang, Wen-Xiong Zhang, Shengfa Ye, Junnian Wei*, and Zhenfeng Xi*, Metalla-aromatics: Planar, Nonplanar, and Spiro, Acc. Chem. Res. 2021, 54, 2323–2333. Haihan Yan, Botao Wu, Yin-Shan Meng*, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis, Structure, and Magnetic Properties of Rare-Earth Bis(diazabutadiene) Diradical Complexes, Inorg. Chem. 2021, 60, 1315–1319. Mingdong Zhong, Xianlu Cui, Botao Wu, Gao-Xiang Wang, Wen-Xiong Zhang, Junnian Wei, Lili Zhao*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Structurally Well-Defined Cobalt Diazenido Complex, CCS Chem. 2021, 3, 856–863. Mingdong Zhong, Junnian Wei, Wen-Xiong Zhang, and Zhenfeng Xi*, Synthesis and Reactivity of Side-Arm Phosphine Functionalized Amidinatosilylene and Amidinatogermylene-supported Nickel(0) Complexes, Organometallics 2021, 41, 310–313. Zhe Huang, Yongliang Zhang, Wen-Xiong Zhang, Junnian Wei*, Shengfa Ye*, and Zhenfeng Xi*, A Tris-spiro Metalla-aromatic System Featuring Craig-Möbius Aromaticity, Nat. Commun. 2021, 12, 1319. Gao-Xiang Wang#, Jianhao Yin#, Jiapeng Li#, Zhu-Bao Yin, Botao Wu, Junnian Wei*, Wen-Xiong Zhang, and Zhenfeng Xi*, Dinitrogen Activation at Cyclopentadienyl-Phosphine-Iron Complexes of Three Different Valences, CCS Chem. 2021, 3, 308–316. Haihan Yan#, Botao Wu#, Xiao-Kun Zhao, Chao Yu, Junnian Wei, Han-Shi Hu, Wen-Xiong Zhang*, and Zhenfeng Xi, Rare-earth Metal Boroxide with Formal Triple Metal-Oxygen Orbital Interaction: Synthesis from B(C6F5)3·H2O and Radical-anion Ligated Rare-earth Metal Amides, CCS Chem. 2020, 2, 2772–2781. ( #Authors contributed equally.) Yu Zheng#, Chang-Su Cao#, Wangyang Ma#, Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins, J. Am. Chem. Soc. 2020, 142, 10705–10714. ( #Authors contributed equally.) Nan Li#, Botao Wu#, Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction, Angew. Chem., Int. Ed. 2020, 59, 8868–8872. ( #Authors contributed equally., Hot Paper) Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction, Chem. Soc. Rev. 2020, 49, 5810–5849. (Invited Review Article) Gen Luo, Shanshan Du, Pan Wang, Fan Liu, Wen-Xiong Zhang*, and Yi Luo*, Fragmentation Mechanism of White Phosphorus: A Theoretical Insight into Multiple Cleavage/Formation of P‒P and P‒C Bonds, Chem. Eur. J. 2020, 26, 13282–13287. Yongliang Zhang, Botao Wu, Mingdong Zhong, Wen-Xiong Zhang*, and Zhenfeng Xi*, Cyclic Bis-alkylidene Complexes of Titanium and Zirconium: Synthesis, Characterization, and Reaction, Chem. Eur. J. 2020, 26, 16472–16479. Nan Li, and Wen-Xiong Zhang*, Molecular Complexes of Emerging Tetravalent Rare-Earth Metals, Chin. J. Chem. 2020, 38, 1449–1450. (Invited Emerging Topic) Nan Li, and Wen-Xiong Zhang*, Frustrated Lewis Pairs: Discovery and Overviews in Catalysis, Chin. J. Chem. 2020, 38, 1360–1370. (Invited Critical Review) Ze-Jie Lv, Junnian Wei, Wen-Xiong Zhang, Ping Chen, Dehui Deng, Zhang-Jie Shi, and Zhenfeng Xi*, Direct Transformation of Dinitrogen: Synthesis of N-Containing Organic Compounds via N−C Bond Formation, Natl. Sci. Rev. 2020, 7, 1564–1583. Zhe Huang, Yu Zheng, Wen-Xiong Zhang, Shengfa Ye*, Liang Deng*, and Zhenfeng Xi*, Dinickelaferrocene: A Ferrocene Analogue with Two Aromatic Nickeloles Realized by Electron Back-Donation from Iron, Angew. Chem., Int. Ed. 2020, 59, 14394–14398. Chao Yu, Mingdong Zhong, Yongliang Zhang, Junnian Wei, Wangyang Ma, Wen-Xiong Zhang, Shengfa Ye*,and Zhenfeng Xi*, Butadienyl Diiron Complexes: Nonplanar Metalla-Aromatics Involving σ-Type Orbital Overlap, Angew. Chem., Int. Ed. 2020, 59, 19048–19053. Chao Yu, Botao Wu, Zhenqiang Yang, Hui Chen, Wen-Xiong Zhang, and Zhenfeng Xi*, Inverse-Sandwich Cyclobutadiene Dinickel Complexes: Synthesis and Structural Characterization, Bull. Chem. Soc. Jpn. 2020, 93, 1314–1318. Chao Yu, Wang Ma, Wen-Xiong Zhang, and Zhenfeng Xi*, Mono- and Bis-Titanium Complexes Bridged by 2-Butene Tetraanion: Synthesis and Structural Characterization, Organometallics 2020, 39, 793–796.