程瑞华 照片

程瑞华

副教授,硕士生导师

所属大学: 华东理工大学

所属学院: 化工学院

邮箱:
rhcheng@ecust.edu.cn

研究领域

(1)新型绿色聚烯烃催化剂的开发、机理研究及应用 (2)CO2 的高效转化和利用,聚(氨)酯的催化合成

近期论文

Pengyuan Qiu, Ruihua Cheng, Zhen Liu, Boping Liu, Boris Tumanskii, Moris S. Eisen, Switching from ethylene polymerization to nonselective oligomerization over a homogeneous model catalyst: A triphenylsiloxy complex of chromium(VI) , Journal of Organometallic Chemistry, 2012,699 , 48 -55.

Pengyuan Qiu, Ruihua Cheng, Boping Liu, Boris Tumanskii, Rami J. Batrice, Mark Botoshansky, Moris S. Eisen, A Triphenylsiloxy Complex of Chromium(II) as a Switchable Catalyst for Ethylene Polymerization and Nonselective Oligomerization, Organometallics, 2011, 30, 2144-2148.

Yun Yang, Zhen Liu, Lei Zhong, Pengyuan Qiu, Qi Dong, Ruihua Cheng, Jeffrey Vanderbilt, Boping Liu, Spin surface crossing between chromium(I)/sextet and chromium(III)/quartet without deprotonation in SNS-Cr mediated ethylene trimerization, Organometallics, 2011, 30 (19), 5297-5302.

Zhen Liu, Lei Zhong, Yun Yang, Ruihua Cheng, and Boping Liu, DFT and CASPT2 Study on the Mechanism of ethylene dimerization over Cr(II)OH+ cation, Journal of Physical Chemistry A, 2011, 115 (28), 8131-8141.

Ruihua Cheng, Chen Xu, Zhen Liu, Qi Dong, Xuelian He, Yuwei Fang, Minoru Terano, Yatao Hu, Thomas J. Pullukat, Boping Liu*, High resolution spectroscopy (XPS, 1H MAS solid state NMR) and DFT investigations on Ti-modified Phillips CrOx/SiO2 catalysts, Journal of Catalysis, 2010, 273, 103-115.

Xiaofang Li, Ruihua Cheng∗, Jun Luo, Qi Dong, Xuelian He, Liuzhong Li, Yongling Yu, Jianwen Da, Boping Liu*,Experimental and theoretical studies on ethylene polymerization using SiO2-supported silyl chromate type catalysts prepared by a green method, Journal of Molecular Catalysis A: Chemical, 2010,330,56-65.

Xiaochun Cao, Ruihua Cheng*, Zhen Liu, Lisong Wang, Qi Dong, Xuelian He, Boping Liu*, DFT and PIO study of the influences of Mo valance state and surface hydroxyl on supported-MoOx catalyst for ethylene polymerization, Journal of Molecular Catalysis A: Chemical, 2010, 321, 50-60.

Ruihua Cheng, Zhen Liu, Pengyuan Qiu, Shiliang Zhang, Boping Liu*,Theoretical modeling on the coordination mechanism of ethylene monomer on various prereduced Cr(II)Ox/SiO2 Phillips polyethylene model catalysts, Chinese Journal of Polymer Science, 2008, 26, 579-587.

Ruihua Cheng, Boping Liu*, Pengyuan Qiu, Shiliang Zhang, Zhen Liu, Toshiaki Taniike, Minoru Terano, Mono- and di- ethylene coordination on a molecular cluster model of prereduced Cr(II)Ox/SiO2 Phillips catalyst, Current Achivements on Heterogeneous Olefin Polymerization Catalysts, edited by B. Liu and M. Terano, Sankeisha. Co., Ltd., Nagoya, 2008, 64-71.

Ruihua Cheng, Yuying Shu, Mingyuan Zheng, Lin Li, Jun Sun, Xiaodong Wang, Tao Zhang*, Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies, Journal of Catalysis, 2007, 249, 397-400.

Ruihua Cheng, Lin Li, Mingyuan Zheng, Yuying Shu, Xiaodong Wang, Aiqin Wang, Tao Zhang, Synthesis and characterization of high surface area molybdenum phosphide, Applied Catalysis A: General, 2007, 316, 160-168.

Ruihua Cheng, Yuying Shu, Lin Li, Jun Sun, Xiaodong Wang, Tao Zhang*, Calorimetry study of CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid, Thermochimica Acta, 2006, 450, 42-46.